Hsu, Chao-Ping and Song, Xueyu and Marcus, R. A. (1997) Time-Dependent Stokes Shift and Its Calculation from Solvent Dielectric Dispersion Data. Journal of Physical Chemistry B, 101 (14). pp. 2546-2551. ISSN 1520-6106. doi:10.1021/jp9630885. https://resolver.caltech.edu/CaltechAUTHORS:20150421-135525609
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Abstract
The time-dependent solvation correlation function (the Stokes shift response function), which describes the solvent response to a sudden change in the charge distribution of a solute molecule, is calculated here directly from experimentally measured dielectric dispersion data, ε(ω), of the solvent. In the calculation a reaction field with the dielectric continuum assumption is used. This simple model is applied to the experimental results of Jimenez et al. for photoexcited coumarin and water as a solvent, and encouraging agreement is obtained using the experimental data on ε(ω).
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| Additional Information: | © 1997 American Chemical Society. Received: October 8, 1996; In Final Form: January 13, 1997. It is a pleasure to acknowledge the support of this research by the National Science Foundation and by the Office of Naval Research. This article is dedicated to the memory of a long-time friend, Heinz Gerischer, whom one of us had the pleasure of knowing for almost 40 years. Heinz was a generous and thoughtful individual whose impact on electrochemistry is enormous. | |||||||||
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| Issue or Number: | 14 | |||||||||
| DOI: | 10.1021/jp9630885 | |||||||||
| Record Number: | CaltechAUTHORS:20150421-135525609 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150421-135525609 | |||||||||
| Official Citation: | Time-Dependent Stokes Shift and Its Calculation from Solvent Dielectric Dispersion Data Chao-Ping Hsu,Xueyu Song,† and, and R. A. Marcus The Journal of Physical Chemistry B 1997 101 (14), 2546-2551 DOI: 10.1021/jp9630885 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 56837 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 21 Apr 2015 22:08 | |||||||||
| Last Modified: | 10 Nov 2021 21:04 |
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