Gregor, Harry P. and Belle, Jack and Marcus, R. A. (1954) Studies on Ion Exchange Resins. IX. Capacity and Specific Volumes of Quaternary Base Anion Exchange Resins. Journal of the American Chemical Society, 76 (7). pp. 1984-1987. ISSN 0002-7863. doi:10.1021/ja01636a085. https://resolver.caltech.edu/CaltechAUTHORS:20150422-164715224
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Abstract
The exchange capacities, wet weights and volumes of a quaternary ammonium anion exchange resin in a number of univalent anionic states including the halide, strong mineral acid anion, hydroxide, chloro-substituted acetate and benzene and naphthalene sulfonate states, were measured. The exchange capacity was the same for all anions, and showed the absence of appreciable adsorption effects. The swelled volume of the resin phase was correlated with the partial molal volumes of the exchange anions. Swelling appears to be determined, to a considerable extent, by ion-pair formation.
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| Additional Information: | © 1954 American Chemical Society. Received November 27, 1953. The authors wish to thank the Signal Corps, U. S. Army, and the Office of Naval Research for the support given this work. Taken in part from the dissertation of J. Belle, submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Chemistry, Polytechnic Institute of Brooklyn, October, 1951. | |||||||||
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| Issue or Number: | 7 | |||||||||
| DOI: | 10.1021/ja01636a085 | |||||||||
| Record Number: | CaltechAUTHORS:20150422-164715224 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150422-164715224 | |||||||||
| Official Citation: | Studies on Ion Exchange Resins. IX. Capacity and Specific Volumes of Quaternary Base Anion Exchange Resins Harry P. Gregor, Jack Belle, and R. A. Marcus Journal of the American Chemical Society 1954 76 (7), 1984-1987 DOI: 10.1021/ja01636a085 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 56897 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 23 Apr 2015 15:28 | |||||||||
| Last Modified: | 10 Nov 2021 21:05 |
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