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Studies on Ion Exchange Resins. IX. Capacity and Specific Volumes of Quaternary Base Anion Exchange Resins

Gregor, Harry P. and Belle, Jack and Marcus, R. A. (1954) Studies on Ion Exchange Resins. IX. Capacity and Specific Volumes of Quaternary Base Anion Exchange Resins. Journal of the American Chemical Society, 76 (7). pp. 1984-1987. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20150422-164715224

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Abstract

The exchange capacities, wet weights and volumes of a quaternary ammonium anion exchange resin in a number of univalent anionic states including the halide, strong mineral acid anion, hydroxide, chloro-substituted acetate and benzene and naphthalene sulfonate states, were measured. The exchange capacity was the same for all anions, and showed the absence of appreciable adsorption effects. The swelled volume of the resin phase was correlated with the partial molal volumes of the exchange anions. Swelling appears to be determined, to a considerable extent, by ion-pair formation.


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http://dx.doi.org/10.1021/ja01636a085DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01636a085PublisherArticle
Additional Information:© 1954 American Chemical Society. Received November 27, 1953. The authors wish to thank the Signal Corps, U. S. Army, and the Office of Naval Research for the support given this work. Taken in part from the dissertation of J. Belle, submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Chemistry, Polytechnic Institute of Brooklyn, October, 1951.
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Funding AgencyGrant Number
U. S. Army, Signal CorpsUNSPECIFIED
Office of Naval Research (ONR)UNSPECIFIED
Record Number:CaltechAUTHORS:20150422-164715224
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150422-164715224
Official Citation:Studies on Ion Exchange Resins. IX. Capacity and Specific Volumes of Quaternary Base Anion Exchange Resins Harry P. Gregor, Jack Belle, and R. A. Marcus Journal of the American Chemical Society 1954 76 (7), 1984-1987 DOI: 10.1021/ja01636a085
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:56897
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:23 Apr 2015 15:28
Last Modified:13 Feb 2019 18:03

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