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Titration of Polyelectrolytes at Higher Ionic Strengths

Marcus, R. A. (1954) Titration of Polyelectrolytes at Higher Ionic Strengths. Journal of Physical Chemistry, 58 (8). pp. 621-623. ISSN 0022-3654 . http://resolver.caltech.edu/CaltechAUTHORS:20150422-165410484

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Abstract

The titration behavior of polyelectrolytes at higher ionic strengths is treated on the basis of the nearest neighbor interaction between the fixed ions. This point of view suggests a quantitative comparison of the behavior of polymeric and dibasic acids. The application of these considerations to existing work on the correlation of viscosity and titration curves of polymeric acids is briefly discussed.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/j150518a008DOIArticle
http://pubs.acs.org/doi/abs/10.1021/j150518a008PublisherArticle
Additional Information:© 1954 American Chemical Society. Received April 19, 1954. The author should like to express his appreciation to Dr. H. Morawetz, who suggested the problem and offered a number of helpful comments.
Record Number:CaltechAUTHORS:20150422-165410484
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150422-165410484
Official Citation:Titration of Polyelectrolytes at Higher Ionic Strengths R. A. Marcus The Journal of Physical Chemistry 1954 58 (8), 621-623 DOI: 10.1021/j150518a008
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:56898
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:23 Apr 2015 15:20
Last Modified:13 Feb 2019 18:03

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