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Protonation of metallocenes by strong acids. Structure of the cation

Curphey, T. J. and Santer, J. O. and Rosenblum, M. and Richards, J. H. (1960) Protonation of metallocenes by strong acids. Structure of the cation. Journal of the American Chemical Society, 82 (19). pp. 5249-5250. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20150428-140300077

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Abstract

Ferrocene recently has been shown to form a stable complex salt of composition (C_(10_H_(10)Fe•HAlCl_4) in the presence of aluminum chloride and hydrogen chloride. This finding, together with the suggestion that the transition state for electrophilic substitution of ferrocene, ruthenocene and osmocene may involve initial interaction of the electrophile with the metal atom, prompted us to examine then.m.r. spectra of these moetallcenes in media of high acidity.


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http://dx.doi.org/10.1021/ja01504a062DOIArticle
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Additional Information:© 1960 American Chemical Society. Received August 10, 1960. This research was supported by grants from the National Science Foundation and the National Institutes of Health (RG-5978-C1). Contribution No. 2610, Caltech Gates and Crellin Laboratories of Chemistry, California Institute of Technology, Pasadena, California.
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Caltech Gates and Crellin Laboratories of Chemistry2610
Record Number:CaltechAUTHORS:20150428-140300077
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150428-140300077
Official Citation:PROTONATION OF METALLOCENES BY STRONG ACIDS. STRUCTURE OF THE CATION T. J. Curphey, J. O. Santer, M. Rosenblum, and J. H. Richards Journal of the American Chemical Society 1960 82 (19), 5249-5250 DOI: 10.1021/ja01504a062
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:57054
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:28 Apr 2015 21:22
Last Modified:13 Feb 2019 18:03

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