Hall, David W. and Richards, John H. (1963) The Acetylation of Some Substituted Ferrocenes. Journal of Organic Chemistry, 28 (6). pp. 1547-1554. ISSN 0022-3263. doi:10.1021/jo01041a026. https://resolver.caltech.edu/CaltechAUTHORS:20150428-161554242
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Abstract
A number of mono- and disubstituted ferrocenes have been acetylated. It has been found that iodine is lost from iodoferrocene under the acetylation conditions employed. Contrary to another report, bromo- and chloroferrocenes are acetylated to give 1'-acetylbromo- and chloroferrocenes in good yield. Acetylation of acetamido- and urethanoferrocenes gives predominantly the heteroannulsrly substituted isomers, and these substituents are deactivating.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1963 American Chemical Society. Received November 15, 1962. D. W. Hall is grateful to the Division of General Medical Sciences of the Public Health Service for a predoctoral research fellowship (GPM 12, 877-Cl). | |||||||||
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| Issue or Number: | 6 | |||||||||
| DOI: | 10.1021/jo01041a026 | |||||||||
| Record Number: | CaltechAUTHORS:20150428-161554242 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150428-161554242 | |||||||||
| Official Citation: | The Acetylation of Some Substituted Ferrocenes David W. Hall and John H. Richards The Journal of Organic Chemistry 1963 28 (6), 1549-1554 DOI: 10.1021/jo01041a026 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 57073 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | INVALID USER | |||||||||
| Deposited On: | 01 May 2015 17:06 | |||||||||
| Last Modified: | 10 Nov 2021 21:07 |
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