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Nuclear magnetic resonance spectra of ferrocenyl carbonium ions

Cais, Michael and Dannenberg, J. J. and Eisenstadt, A. and Levenberg, M. L. and Richards, J. H. (1966) Nuclear magnetic resonance spectra of ferrocenyl carbonium ions. Tetrahedron Letters, 7 (15). pp. 1695-1701. ISSN 0040-4039. https://resolver.caltech.edu/CaltechAUTHORS:20150429-092148166

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Abstract

Recently it has been suggested (1) that the properties of ɑ-metallocenyl carbonium ions can be best explained in terms of mesomeric ring effects not involving metal participation (2). The Ware and Traylor interpretation (1) suggests Ib as the major mesomeric form contributing to the resonance stabilization of the ion I, whereas the metal participation concept (2) envisages the contribution from Ic as the major stabilizing factor.


Item Type:Article
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http://dx.doi.org/10.1016/S0040-4039(01)99779-5DOIArticle
http://www.sciencedirect.com/science/article/pii/S0040403901997795PublisherArticle
Additional Information:© 1966 Pergamon Press Ltd. Received 11 February 1966, Available online 8 March 2001. We should like to thank Mrs. R. Stanaszek of the Abbott Laboratories for taking some n. m. r. spectra, the U. S. Public Health Service (Grant No. 5F1 GM 21, 655) for a predoctoral fellowship to one of us (J. J. Dannenberg), the National Science Foundation for support of the research (NSF G24995) at the California Institute of Technology, and the Air Force Materials Laboratory, Research and Technology Division, AFSC, European Office of Aerospace Research, United States Air Force for support of the research [Contract No. AF 61(052)-752] at the Technion-Israel Institute of Technology.
Funders:
Funding AgencyGrant Number
U.S. Public Health Service5F1 GM 21, 655
NSFG24995
Air Force Materials LaboratoryUNSPECIFIED
European Office of Aerospace ResearchUNSPECIFIED
U.S. Air Force AF 61(052)-752
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Caltech Gates and Crellin Laboratories of Chemistry3311
Issue or Number:15
Record Number:CaltechAUTHORS:20150429-092148166
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150429-092148166
Official Citation:Michael Cais, J.J. Dannenberg, A. Einsenstadt, M.I. Levenberg, J.H. Richards, Nuclear magnetic resonance spectra of ferrocenyl carbonium ions, Tetrahedron Letters, Volume 7, Issue 15, 1966, Pages 1695-1701, ISSN 0040-4039, http://dx.doi.org/10.1016/S0040-4039(01)99779-5. (http://www.sciencedirect.com/science/article/pii/S0040403901997795)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:57084
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:29 Apr 2015 17:17
Last Modified:03 Oct 2019 08:20

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