Hall, David W. and Hill, E. Alexander and Richards, John H. (1968) Solvolysis of heteroannularly substituted methylferrocenylcarbinyl acetates. Journal of the American Chemical Society, 90 (18). pp. 4972-4976. ISSN 0002-7863. doi:10.1021/ja01020a034. https://resolver.caltech.edu/CaltechAUTHORS:20150429-142313160
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20150429-142313160
Abstract
The nature of the transmission of substituent effects from one cyclopentadienyl ring of ferrocene to a reaction center on the other ring was investigated by means of solvolysis studies on heteroannularly substituted methylferrocenylcarbinyl acetates. The evidence indicates that inductive or field effects predominate, and that resonance interactions play at most a minor role. A linear relationship exists between substituent effects in the solvolysis reaction and the reversible quarter-wave potentials of the appropriately substituted ferrocenes.
| Item Type: | Article | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| |||||||||
| Additional Information: | © 1968 American Chemical Society. Received January 25, 1968. This investigation was supported by a grant from the National Science Foundation NSF-CP 5190) and the Paint Research Institute. | |||||||||
| Funders: |
| |||||||||
| Other Numbering System: |
| |||||||||
| Issue or Number: | 18 | |||||||||
| DOI: | 10.1021/ja01020a034 | |||||||||
| Record Number: | CaltechAUTHORS:20150429-142313160 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150429-142313160 | |||||||||
| Official Citation: | Solvolysis of heteroannularly substituted methylferrocenylcarbinyl acetates David W. Hall, E. Alexander Hill, and John H. Richards Journal of the American Chemical Society 1968 90 (18), 4972-4976 DOI: 10.1021/ja01020a034 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 57096 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 01 May 2015 17:05 | |||||||||
| Last Modified: | 10 Nov 2021 21:08 |
Repository Staff Only: item control page
