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An Analysis of the Nuclear Magnetic Resonance Spectra of Substituted Ferrocenes

Levenberg, Milton I. and Richards, J. H. (1964) An Analysis of the Nuclear Magnetic Resonance Spectra of Substituted Ferrocenes. Journal of the American Chemical Society, 86 (13). pp. 2634-2637. ISSN 0002-7863. doi:10.1021/ja01067a023. https://resolver.caltech.edu/CaltechAUTHORS:20150429-145443614

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Abstract

A detailed analysis of the n.m.r. spectra of a series of alkylacetylferrocenes in a variety of solvents has been carried out. This has allowed a determination of the coupling constants between the various protons in these substances. For protons attached to the same ring, the following values are generally observed: J_(23) ~2.5 c.p.s. and J_(24) ~1.3 c.p.s. The magnetic anisotropy of the carbonyl group in 2-acetyl-1,1'-trimethylcneferrocene is also discussed.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01067a023DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01067a023PublisherArticle
Additional Information:© 1964 American Chemical Society. Received January 18, 1964.
Funders:
Funding AgencyGrant Number
Alfred P. Sloan FoundationUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Department of Chemistry3070
Issue or Number:13
DOI:10.1021/ja01067a023
Record Number:CaltechAUTHORS:20150429-145443614
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150429-145443614
Official Citation:An Analysis of the Nuclear Magnetic Resonance Spectra of Substituted Ferrocenes Milton I. Levenberg and J. H. Richards Journal of the American Chemical Society 1964 86 (13), 2634-2637 DOI: 10.1021/ja01067a023
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:57097
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:30 Apr 2015 20:47
Last Modified:10 Nov 2021 21:08

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