CaltechAUTHORS
  A Caltech Library Service

Ion Pairing and Electron Transfer

Marcus, R. A. (1998) Ion Pairing and Electron Transfer. Journal of Physical Chemistry B, 102 (49). pp. 10071-10077. ISSN 1089-5647. https://resolver.caltech.edu/CaltechAUTHORS:20150513-165258796

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20150513-165258796

Abstract

Several scenarios are considered for the effect of electrolytes, specifically for ion pairing, on the rates of electron transfer reactions:  (i) electron transfer followed by ion transfer, (ii) ion-pair dissociation followed by electron transfer, or (iii) ion transfer accompanying the electron transfer. The latter may involve fast or slow (diffusive) ionic motion. A distinction is made between ion reorganization (case (iii)) and the formation of real chemical intermediates. The ion pairs themselves may be tight (contact) or loose (solvent separated). The discussion is illustrated with an example in the literature. Differences in degree in behavior of intramolecular and intermolecular electron transfer, due to differences in extent of ionic motion, are noted.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/jp9834457DOIArticle
http://pubs.acs.org/doi/abs/10.1021/jp9834457PublisherArticle
ORCID:
AuthorORCID
Marcus, R. A.0000-0001-6547-1469
Additional Information:© 1998 American Chemical Society. Received August 21, 1998; In Final Form October 12, 1998. It is a pleasure to acknowledge the support of this research by the Office of Naval Research and by the National Science Foundation, and the very helpful comments of Piotr Piotrowiak. This article is dedicated to Allen Bard on the occasion of his 65th birthday. Al’s contributions to the electron transfer field have been immense, continually inventive and pioneering, and I am happy to participate in this Festschrift volume dedicated to him.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
NSFUNSPECIFIED
Issue or Number:49
Record Number:CaltechAUTHORS:20150513-165258796
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150513-165258796
Official Citation:Marcus, R. A. (1998). Ion Pairing and Electron Transfer. The Journal of Physical Chemistry B, 102(49), 10071-10077. doi: 10.1021/jp9834457
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:57516
Collection:CaltechAUTHORS
Deposited By: Joanne McCole
Deposited On:14 May 2015 21:55
Last Modified:22 Nov 2019 09:58

Repository Staff Only: item control page