Marcus, R. A. (1992) Schrödinger equation for strongly interacting electron-transfer systems. Journal of Physical Chemistry, 96 (4). pp. 1753-1757. ISSN 0022-3654. doi:10.1021/j100183a048. https://resolver.caltech.edu/CaltechAUTHORS:20150514-110110841
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20150514-110110841
Abstract
The Schrödinger equation for strongly interacting electron-transfer systems is described, the eigenvalues depending on a dielectric polarization function P(r) for the medium, on the internal coordinates q, and, when the electron transfer is coupled to a dissociation, on a generalized coordinate Q. A choice of the reaction coordinate for the variation of P(r), q, and Q, so as to reach the saddle-point, and the calculation of the free energy of activation are described. The question of suitable data on the solvent dependence of strong-overlap systems is also considered.
| Item Type: | Article | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| |||||||||
| ORCID: |
| |||||||||
| Additional Information: | © 1992 American Chemical Society. Received: July 23, 1991. It is a pleasure to acknowledge helpful discussions with David Chandler, Casey Hynes and Hyung Kim and to acknowledge the support of this research by the Office of Naval Research. | |||||||||
| Funders: |
| |||||||||
| Other Numbering System: |
| |||||||||
| Issue or Number: | 4 | |||||||||
| DOI: | 10.1021/j100183a048 | |||||||||
| Record Number: | CaltechAUTHORS:20150514-110110841 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150514-110110841 | |||||||||
| Official Citation: | Schrodinger equation for strongly interacting electron-transfer systems R. A. Marcus The Journal of Physical Chemistry 1992 96 (4), 1753-1757 DOI: 10.1021/j100183a048 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 57529 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 14 May 2015 18:19 | |||||||||
| Last Modified: | 10 Nov 2021 21:51 |
Repository Staff Only: item control page
