Marcus, R. A. (1990) Theory of charge-transfer spectra in frozen media. Journal of Physical Chemistry, 94 (12). pp. 4963-4966. ISSN 0022-3654. doi:10.1021/j100375a038. https://resolver.caltech.edu/CaltechAUTHORS:20150519-090711379
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Abstract
Absorption and fluorescence maxima of charge-transfer spectra in frozen media are treated, noting that only some of the nuclear motions for liquid medium are frozen in corresponding solid or glassy phase. Account is taken of the fact that the conditions under which the static dielectric constant of the frozen phase is measured do not usually correspond to those in which the initial state of the solute system is prepared. Expressions for the maxima are obtained in terms of the optical and static dielectric constants of the liquid and frozen (solid or glassy) phases. Comparison of Stokes shifts hv_a-hv_f at conventional fluorescence times in frozen media with Stokes shifts at picosecond or subpicosecond times in liquid media would be of interest.
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| Additional Information: | © 1990 American Chemical Society. Received: November 10, 1989; In Final Form: February 9, 1990. It is a pleasure to acknowledge the support of this research by the National Science Foundation and by the Office of Naval Research. | |||||||||
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| Issue or Number: | 12 | |||||||||
| DOI: | 10.1021/j100375a038 | |||||||||
| Record Number: | CaltechAUTHORS:20150519-090711379 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150519-090711379 | |||||||||
| Official Citation: | Theory of charge-transfer spectra in frozen media R. A. Marcus The Journal of Physical Chemistry 1990 94 (12), 4963-4966 DOI: 10.1021/j100375a038 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 57636 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 19 May 2015 18:42 | |||||||||
| Last Modified: | 10 Nov 2021 21:53 |
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