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Free Energy of Nonequilibrium Polarization Systems. 4. A Formalism Based on the Nonequilibrium Dielectric Displacement

Marcus, R. A. (1994) Free Energy of Nonequilibrium Polarization Systems. 4. A Formalism Based on the Nonequilibrium Dielectric Displacement. Journal of Physical Chemistry, 98 (29). pp. 7170-7174. ISSN 0022-3654. https://resolver.caltech.edu/CaltechAUTHORS:20150608-150915281

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Abstract

An expression for the free energy of nonequilibrium polarization systems, valid in the presence or absence of dielectric images, is derived using the nonequilibrium dielectric displacement and electric field vectors. The results are compared with those based on the nonequilibrium polarization vector (Part I). For the case of longitudinal polarization they are equivalent. However, the present expression is simpler and more compact. The results are compared with others in the literature.


Item Type:Article
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http://dx.doi.org/10.1021/j100080a012DOIArticle
http://pubs.acs.org/doi/abs/10.1021/j100080a012PublisherArticle
ORCID:
AuthorORCID
Marcus, R. A.0000-0001-6547-1469
Additional Information:© 1994 American Chemical Society. Received: March 18, 1994; In Final Form: May 9, 1994. I am indebted to the Office of Naval Research and the National Science Foundation for the support of this research. It is a pleasure to dedicate this article to Professor C. N. R. Rao, on the occasion of his 60th birthday.
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Office of Naval Research (ONR)UNSPECIFIED
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Caltech Noyes Laboratory of Chemical Physics8934
Issue or Number:29
Record Number:CaltechAUTHORS:20150608-150915281
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150608-150915281
Official Citation:Free Energy of Nonequilibrium Polarization Systems. 4. A Formalism Based on the Nonequilibrium Dielectric Displacement R. A. Marcus The Journal of Physical Chemistry 1994 98 (29), 7170-7174 DOI: 10.1021/j100080a012
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:58094
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:09 Jun 2015 13:42
Last Modified:22 Nov 2019 09:58

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