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Superexchange versus an intermediate BChl− mechanism in reaction centers of photosynthetic bacteria

Marcus, R. A. (1987) Superexchange versus an intermediate BChl− mechanism in reaction centers of photosynthetic bacteria. Chemical Physics Letters, 133 (6). pp. 471-477. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20150617-100539459

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Abstract

Kinetic and singlet-triplet data are used to treat the mechanism of electron transfer for BChl*_2-BChl-BPh in bacterial photosynthetic reaction centers. The data favor a two-step transfer rather than a superexchange single step.


Item Type:Article
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http://dx.doi.org/10.1016/0009-2614(87)80061-1 DOIArticle
http://www.sciencedirect.com/science/article/pii/0009261487800611PublisherArticle
ORCID:
AuthorORCID
Marcus, R. A.0000-0001-6547-1469
Additional Information:© 1987 Elsevier Science Publishers B.V. Received 15 October 1986, in final form 18 December 1986. It is a pleasure to acknowledge the support of this research by the National Science Foundation. The research was initiated while the author was a Leland J. Haworth Distinguished Scientist at Brookhaven National Laboratory. I am indebted to Dr. Norman Sutin and his colleagues for their gracious hospitality and many stimulating discussions. I am particularly indebted, too, to Dr. Jack Fajer of BNL, who called my attention to the experimental results in ref. [8], and to Drs. S. Boxer and W.W. Parsons for their helpful comments.
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Issue or Number:6
Record Number:CaltechAUTHORS:20150617-100539459
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150617-100539459
Official Citation:R.A. Marcus, Superexchange versus an intermediate BChl− mechanism in reaction centers of photosynthetic bacteria, Chemical Physics Letters, Volume 133, Issue 6, 6 February 1987, Pages 471-477, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(87)80061-1. (http://www.sciencedirect.com/science/article/pii/0009261487800611)
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ID Code:58315
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:17 Jun 2015 17:25
Last Modified:22 Nov 2019 09:58

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