Marcus, R. A. and Sumi, H. (1986) Solvent dynamics and vibrational effects in electron transfer reactions. Journal of Electroanalytical Chemistry, 204 (1-2). pp. 59-67. ISSN 0022-0728. doi:10.1016/0022-0728(86)80507-1. https://resolver.caltech.edu/CaltechAUTHORS:20150617-130217766
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Abstract
Intramolecular vibrational effects can modify considerably the effect of solvent dynamics on the rates of electron transfer reactions, even for a fixed free energy barrier. Results of a previous paper by the authors are applied in an approximate way to provide a simplified formula for the reaction rate. The formula includes these effects and reduces to a well-known one of Kramers under a appropriate conditions and when, in addition, vibrational effects are absent.
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| Additional Information: | © 1986 Eisevier Sequoia S.A. Received 2nd January 1986. It is a pleasure to acknowledge the support of this research by the National Science Foundation. | |||||||||
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| Issue or Number: | 1-2 | |||||||||
| DOI: | 10.1016/0022-0728(86)80507-1 | |||||||||
| Record Number: | CaltechAUTHORS:20150617-130217766 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150617-130217766 | |||||||||
| Official Citation: | R.A. Marcus, H. Sumi, Solvent dynamics and vibrational effects in electron transfer reactions, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Volume 204, Issues 1–2, 10 June 1986, Pages 59-67, ISSN 0022-0728, http://dx.doi.org/10.1016/0022-0728(86)80507-1. (http://www.sciencedirect.com/science/article/pii/0022072886805071) | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58324 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 17 Jun 2015 20:33 | |||||||||
| Last Modified: | 10 Nov 2021 22:03 |
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