Molina, M. J. and Colussi, A. J. and Molina, L. T. and Schindler, R. N. and Tso, T.-L. (1990) Quantum yield of chlorine-atom formation in the photodissociation of chlorine peroxide (ClOOCl) at 308 nm. Chemical Physics Letters, 173 (4). pp. 310-315. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20150619-144323323
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Abstract
The production of Cl atoms in the laser flash photolysis of ClOOCl at 308 nm has been investigated by time-resolved atomic resonance fluorescence at 235 K. A value of φ = 1.03 ± 0.12 has been obtained for the primary quantum yield based on an absorption cross section ratio σ_(245)/σ_(308) = 22 for ClOOCl at 245 and 308 nm.
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| Additional Information: | © 1990 Elsevier Science Publishers B.V. Received 1 June 1990; in final form 8 July 1990. The work described here was performed at the Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA under a contract with the National Aeronautics and Space Administration. | |||||||||||||||||||||
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| Issue or Number: | 4 | |||||||||||||||||||||
| Record Number: | CaltechAUTHORS:20150619-144323323 | |||||||||||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150619-144323323 | |||||||||||||||||||||
| Official Citation: | M.J. Molina, A.J. Colussi, L.T. Molina, R.N. Schindler, T.-L. Tso, Quantum yield of chlorine-atom formation in the photodissociation of chlorine peroxide (ClOOCl) at 308 nm, Chemical Physics Letters, Volume 173, Issue 4, 12 October 1990, Pages 310-315, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(90)85275-H. (http://www.sciencedirect.com/science/article/pii/000926149085275H) | |||||||||||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||||||||||||||
| ID Code: | 58384 | |||||||||||||||||||||
| Collection: | CaltechAUTHORS | |||||||||||||||||||||
| Deposited By: | Tony Diaz | |||||||||||||||||||||
| Deposited On: | 20 Jun 2015 01:06 | |||||||||||||||||||||
| Last Modified: | 03 Oct 2019 08:35 |
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