Clemmer, D. E. and Dalleska, N. F. and Armentrout, P. B. (1991) Reaction of Zn^+ with NO_2. The gas-phase thermochemistry of ZnO. Journal of Chemical Physics, 95 (10). pp. 7263-7268. ISSN 0021-9606. doi:10.1063/1.461403. https://resolver.caltech.edu/CaltechAUTHORS:20150622-144459008
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Abstract
The homolytic bond dissociation energies of ZnO and ZnO^+ have been determined by using guided ion‐beam mass spectrometry to measure the kinetic‐energy dependence of the endothermic reactions of Zn^+ with nitrogen dioxide. The data are interpreted to yield the bond energy for ZnO, D^0_0=1.61±0.04 eV, a value considerably lower than previous experimental values, but in much better agreement with theoretical calculations. We also obtain D^0_0(ZnO^+)=1.67±0.05 eV, in good agreement with previous results. Other thermochemistry derived in this study is D^0_0(Zn^+–NO)=0.79±0.10 eV and the ionization energies, IE(ZnO)=9.34±0.02 eV and IE(NO_2)=9.57±0.04 eV.
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| Alternate Title: | Reaction of Zn+ with NO2. The gas-phase thermochemistry of ZnO | |||||||||
| Additional Information: | © 1991 American Institute of Physics. (Received 24 June 1991; accepted 2 August 1991). This work is supported by the National Science Foundation, Grant No. CHE 8917980. We are also grateful to James Chou, Kevin Glaeske, and Carl Howard for advice about purifying and handling NO_2. | |||||||||
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| Issue or Number: | 10 | |||||||||
| DOI: | 10.1063/1.461403 | |||||||||
| Record Number: | CaltechAUTHORS:20150622-144459008 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150622-144459008 | |||||||||
| Official Citation: | Reaction of Zn+ with NO2. The gas‐phase thermochemistry of ZnO Clemmer, D. E. and Dalleska, N. F. and Armentrout, P. B., The Journal of Chemical Physics, 95, 7263-7268 (1991), DOI:http://dx.doi.org/10.1063/1.461403 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58424 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 22 Jun 2015 22:11 | |||||||||
| Last Modified: | 10 Nov 2021 22:04 |
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