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Very low pressure pyrolysis of phenylacetic acid

Colussi, A. J. and Amorebieta, V. T. and Grela, M. A. (1992) Very low pressure pyrolysis of phenylacetic acid. Journal of the Chemical Society. Faraday Transactions, 88 (15). pp. 2125-2127. ISSN 0956-5000. doi:10.1039/FT9928802125. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154806039

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Abstract

A Kinetic study of the very low pressure thermolysis of phenylacetic acid above 900 K reveals that its decomposition occurs in a concerted manner, yielding toluene and carbon dioxide, probably via a four-centre transition state [reaction (1)] [graphic omitted] with log[k_∞(1)/s^(–1)]=[(13 ± 0.3)–(12 200 ± 500)]/T.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1039/FT9928802125DOIArticle
http://pubs.rsc.org/en/Content/ArticleLanding/1992/FT/ft9928802125PublisherArticle
ORCID:
AuthorORCID
Colussi, A. J.0000-0002-3400-4101
Additional Information:© 1992 Royal Society of Chemistry. Paper 2/01513G; Received 23rd March, 1992.
Issue or Number:15
DOI:10.1039/FT9928802125
Record Number:CaltechAUTHORS:20150623-154806039
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150623-154806039
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:58514
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:25 Jun 2015 22:45
Last Modified:10 Nov 2021 22:06

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