Colussi, A. J. and Amorebieta, V. T. and Grela, M. A. (1992) Very low pressure pyrolysis of phenylacetic acid. Journal of the Chemical Society. Faraday Transactions, 88 (15). pp. 2125-2127. ISSN 0956-5000. doi:10.1039/FT9928802125. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154806039
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Abstract
A Kinetic study of the very low pressure thermolysis of phenylacetic acid above 900 K reveals that its decomposition occurs in a concerted manner, yielding toluene and carbon dioxide, probably via a four-centre transition state [reaction (1)] [graphic omitted] with log[k_∞(1)/s^(–1)]=[(13 ± 0.3)–(12 200 ± 500)]/T.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1992 Royal Society of Chemistry. Paper 2/01513G; Received 23rd March, 1992. | |||||||||
| Issue or Number: | 15 | |||||||||
| DOI: | 10.1039/FT9928802125 | |||||||||
| Record Number: | CaltechAUTHORS:20150623-154806039 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150623-154806039 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58514 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 25 Jun 2015 22:45 | |||||||||
| Last Modified: | 10 Nov 2021 22:06 |
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