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Induced ClO vacuum ultraviolet fluorescence

Colussi, A. J. and Sander, S. P. (1991) Induced ClO vacuum ultraviolet fluorescence. Chemical Physics Letters, 187 (1-2). pp. 85-92. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154807222

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Abstract

Some vibronic transitions of ClO such as G(ν′=11)←X(ν″=10), G(ν′=5)←X(ν″=3) and H(ν′=4)←X(ν″=2), which promote overtones of X(^2Π^(3/2)) to bound Rydberg states, are nearly resonant with the 130.6 nm O-atom emission line and possess sizable Franck—Condon factors. On this basis broadband detection of “O atom” fluorescence in experiments involving vibrationally excited ClO(X) is ascribed to the radiative decay of ClO(G, H) rather than to the formation of O atoms; these observations raise the probability of monitoring ClO(X; ν=0) by VUV induced fluorescence.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0009-2614(91)90489-VDOIArticle
http://www.sciencedirect.com/science/article/pii/000926149190489VPublisherArticle
ORCID:
AuthorORCID
Colussi, A. J.0000-0002-3400-4101
Sander, S. P.0000-0003-1424-3620
Additional Information:© 1991 Elsevier. Received 23 May 1991; in final form 9 September 1991. The work described here was performed at the Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA, under a contract with the National Aeronautics and Space Administration.
Funders:
Funding AgencyGrant Number
National Research Council of CanadaUNSPECIFIED
NASA/JPL/CaltechUNSPECIFIED
Issue or Number:1-2
Record Number:CaltechAUTHORS:20150623-154807222
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150623-154807222
Official Citation:A.J. Colussi, S.P. Sander, Induced ClO vacuum ultraviolet fluorescence, Chemical Physics Letters, Volume 187, Issues 1–2, 29 November 1991, Pages 85-92, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(91)90489-V. (http://www.sciencedirect.com/science/article/pii/000926149190489V)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:58518
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:26 Jun 2015 14:31
Last Modified:03 Oct 2019 08:37

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