Colussi, A. J. and Sander, S. P. and Friedl, R. R. (1991) Thermodynamics of acetylene van der Waals dimerization. Chemical Physics Letters, 178 (5-6). pp. 497-503. ISSN 0009-2614. doi:10.1016/0009-2614(91)87009-Z. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154807470
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Abstract
Integrated band intensities of the 620 cm^(−1) absorption in (C_2H_2)_2 have been measured by FTIR spectroscopy at constant acetylene pressure between 198 and 273 K. These data, in conjunction with ab initio results for (C_2H_2)_2, have been used for the statistical evaluation of the equilibrium constant K_p(T) for acetylene cluster dimerization. Present results are used to clarify the role of molecular clusters in chemical systems at or near equilibrium, in particular in Titan's stratosphere.
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| Additional Information: | © 1991 Elsevier. Received 12 December 1990. The work described here was performed at the Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA under a contract with the National Aeronautics and Space Administration. We thank Professor Y.L. Yung for a preprint of ref. [15] and for his interest in this work. | |||||||||
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| Issue or Number: | 5-6 | |||||||||
| DOI: | 10.1016/0009-2614(91)87009-Z | |||||||||
| Record Number: | CaltechAUTHORS:20150623-154807470 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150623-154807470 | |||||||||
| Official Citation: | A.J. Colussi, S.P. Sander, R.R. Friedl, Thermodynamics of acetylene van der Waals dimerization, Chemical Physics Letters, Volume 178, Issues 5–6, 5 April 1991, Pages 497-503, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(91)87009-Z. (http://www.sciencedirect.com/science/article/pii/000926149187009Z) | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58519 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 26 Jun 2015 14:29 | |||||||||
| Last Modified: | 10 Nov 2021 22:06 |
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