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Heterogeneous decomposition of trichlorofluoromethane on carbonaceous surfaces

Colussi, Agustin J. and Amorebieta, Valentin T. (1987) Heterogeneous decomposition of trichlorofluoromethane on carbonaceous surfaces. Journal of the Chemical Society. Faraday Transactions 1: Physical Chemistry in Condensed Phases, 83 (9). pp. 3055-3059. ISSN 0300-9599. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154810330

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Abstract

The interaction of trichlorofluoromethane with activated charcoal has been investigated by dynamic mass spectrometry up to 750 K. Prior physical adsorption, revealed in programmed desorption experiments, is followed by irreversible first-order decay with formation of nearly equimolar amounts of HCl above 550 K. This unexpectedly fast process has an apparent activation energy of only 59.4 kJ mol^(–1) and is demonstrably catalytic. The mechanism of Cl_3CF decomposition on carbon surfaces and its possible impact on atmospheric chemistry are discussed.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1039/F19878303055DOIArticle
http://pubs.rsc.org/en/Content/ArticleLanding/1987/F1/F19878303055PublisherArticle
ORCID:
AuthorORCID
Colussi, Agustin J.0000-0002-3400-4101
Additional Information:© 1987 Royal Society of Chemistry. Paper 6/2493; Received 31st December, 1986.
Issue or Number:9
Record Number:CaltechAUTHORS:20150623-154810330
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150623-154810330
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:58530
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:24 Jun 2015 22:02
Last Modified:03 Oct 2019 08:37

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