Ghibaudi, E. and Colussi, A. J. and Christe, Karl O. (1985) Extended correlation between O-F bond energies and ^(19)F NMR chemical shifts in fluoroxy compounds. Inorganic Chemistry, 24 (18). p. 2869. ISSN 0020-1669. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154811928
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Abstract
We wish to report now that an extended set of data, including an experimental measurement of Φ in NO_2OF (Φ = 220) together with existing values for F_2O_2 (D_(O-F) = 18 kcal/mol; Φ = 825) and FOH (54 kcal/mol; 21 ppm), confirms the above conclusions but requires an improved correlation to account for the extremely large spans of both parameters.
| Item Type: | Article | |||||||||
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| Alternate Title: | Extended correlation between oxygen-fluorine bond energies and fluorine-19 NMR chemical shifts in fluoroxy compounds | |||||||||
| Additional Information: | © 1985 American Chemical Society. Received October 2, 1984. K.O.C. is grateful to the Office of Naval Research for financial support. | |||||||||
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| Issue or Number: | 18 | |||||||||
| Record Number: | CaltechAUTHORS:20150623-154811928 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150623-154811928 | |||||||||
| Official Citation: | Extended correlation between oxygen-fluorine bond energies and fluorine-19 NMR chemical shifts in fluoroxy compounds E. Ghibaudi, A. J. Colussi, and Karl O. Christe Inorganic Chemistry 1985 24 (18), 2869-2869 DOI: 10.1021/ic00212a039 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58536 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 24 Jun 2015 21:45 | |||||||||
| Last Modified: | 03 Oct 2019 08:37 |
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