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Extended correlation between O-F bond energies and ^(19)F NMR chemical shifts in fluoroxy compounds

Ghibaudi, E. and Colussi, A. J. and Christe, Karl O. (1985) Extended correlation between O-F bond energies and ^(19)F NMR chemical shifts in fluoroxy compounds. Inorganic Chemistry, 24 (18). p. 2869. ISSN 0020-1669. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154811928

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Abstract

We wish to report now that an extended set of data, including an experimental measurement of Φ in NO_2OF (Φ = 220) together with existing values for F_2O_2 (D_(O-F) = 18 kcal/mol; Φ = 825) and FOH (54 kcal/mol; 21 ppm), confirms the above conclusions but requires an improved correlation to account for the extremely large spans of both parameters.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ic00212a039DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ic00212a039PublisherArticle
ORCID:
AuthorORCID
Colussi, A. J.0000-0002-3400-4101
Alternate Title:Extended correlation between oxygen-fluorine bond energies and fluorine-19 NMR chemical shifts in fluoroxy compounds
Additional Information:© 1985 American Chemical Society. Received October 2, 1984. K.O.C. is grateful to the Office of Naval Research for financial support.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
Issue or Number:18
Record Number:CaltechAUTHORS:20150623-154811928
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150623-154811928
Official Citation:Extended correlation between oxygen-fluorine bond energies and fluorine-19 NMR chemical shifts in fluoroxy compounds E. Ghibaudi, A. J. Colussi, and Karl O. Christe Inorganic Chemistry 1985 24 (18), 2869-2869 DOI: 10.1021/ic00212a039
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:58536
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:24 Jun 2015 21:45
Last Modified:03 Oct 2019 08:37

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