Brusa, M. A. and Perissinotti, L. J. and Colussi, A. J. (1985) Electron spin resonance kinetic studies of malonyl radical self-decay and oxidation reactions by cerium(IV) and bromate in acid aqueous media. The role of free radicals in the Belousov-Zhabotinskii oscillator. Journal of Physical Chemistry, 89 (9). pp. 1572-1574. ISSN 0022-3654. doi:10.1021/j100255a006. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154812181
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20150623-154812181
Abstract
Kinetics of selected reactions involving malonyl radicals (M), generated by Ce(IV) oxidation of malonic acid in acid aqueous media, have been studied by steady-state electron spin resonance under stopped-flow conditions. Rate constants for second-order radical self-decay, k_2(M+M) = 3.2 x 10^9, oxidation by bromate, k_4(M+BrO_3^-) = 6.7 x 10^3, and an upper limit for its oxidation by Ce(IV), k_3(M+Ce(Iv)) ≤ 1.2 x 10^5 M^(-1) s^(+1), have been obtained at 298 K. Some of the consequences of the present results on the mechanism of the Belousov-Zhabotinskii oscillator are examined.
| Item Type: | Article | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| |||||||||
| ORCID: |
| |||||||||
| Additional Information: | © 1985 American Chemical Society. (Received: January 4, 1985) Generous support by CIC of Argentina is gratefully acknowledged. | |||||||||
| Funders: |
| |||||||||
| Issue or Number: | 9 | |||||||||
| DOI: | 10.1021/j100255a006 | |||||||||
| Record Number: | CaltechAUTHORS:20150623-154812181 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150623-154812181 | |||||||||
| Official Citation: | Electron spin resonance kinetic studies of malonyl radical self-decay and oxidation reactions by cerium(IV) and bromate in acid aqueous media. The role of free radicals in the Belousov-Zhabotinskii oscillator M. A. Brusa, L. J. Perissinotti, and A. J. Colussi The Journal of Physical Chemistry 1985 89 (9), 1572-1574 DOI: 10.1021/j100255a006 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58537 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 24 Jun 2015 20:45 | |||||||||
| Last Modified: | 10 Nov 2021 22:06 |
Repository Staff Only: item control page
