Grela, M. A. and Amorebieta, V. T. and Colussi, A. J. (1985) Very low pressure pyrolysis of furan, 2-methylfuran and 2,5-dimethylfuran. The stability of the furan ring. Journal of Physical Chemistry, 89 (1). pp. 38-41. ISSN 0022-3654. doi:10.1021/j100247a011. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154812476
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Abstract
Furan (F), 2-methylfuran (MF), and 2,5-dimethylfuran (DMF) decompose between 1050 and 1270 K by ring breakdown unimolecular reactions. Loss of carbon monoxide is either the exclusive process or a major one in the case of F and MF or DMF decompositions, respectively. A common mechanism involving skeletal isomerization of the furans via cyclopropenylcarbonyl intermediates competing with decomposition through stabilized biradicals is proposed. The analysis of kinetic data leads to similar overall activation parameters for the three furans.
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| Additional Information: | © 1985 American Chemical Society. (Received: June 8, 1984) This work was supported with grants from CIC, SUBCYT, and CONICET of Argentina. Mr. E. F. Valla provided valuable technical assistance. | |||||||||
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| Issue or Number: | 1 | |||||||||
| DOI: | 10.1021/j100247a011 | |||||||||
| Record Number: | CaltechAUTHORS:20150623-154812476 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150623-154812476 | |||||||||
| Official Citation: | Very low pressure pyrolysis of furan, 2-methylfuran and 2,5-dimethylfuran. The stability of the furan ring M. A. Grela, V. T. Amorebieta, and A. J. Colussi The Journal of Physical Chemistry 1985 89 (1), 38-41 DOI: 10.1021/j100247a011 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58538 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 24 Jun 2015 20:58 | |||||||||
| Last Modified: | 10 Nov 2021 22:06 |
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