Amorebieta, V. T. and Colussi, A. J. (1984) Low-level vibrational relaxation in single gas-surface encounters. Molecular structure, surface, and temperature effects. Journal of Physical Chemistry, 88 (19). pp. 4284-4287. ISSN 0022-3654. doi:10.1021/j150663a019. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154813027
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Abstract
Direct measurement of the vibrational temperatures attained by different gases after single encounters with hot silica or platinum surfaces at T_S have been obtained by modulated-beam mass spectrometry. Vibrational energy accommodation coefficients a, for n-butane, n-octane, and 1-chlorobutane are smaller than one over both surfaces, slightly increase with molecular size or polarity, and are nearly independent of T_S between 350 and 700 K. Relaxation is more efficient on platinum.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1984 American Chemical Society. (Received: February 24, 1984) This work was supported by grants from CIC, SUBCYT, and CONICET of Argentina. | |||||||||
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| Issue or Number: | 19 | |||||||||
| DOI: | 10.1021/j150663a019 | |||||||||
| Record Number: | CaltechAUTHORS:20150623-154813027 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150623-154813027 | |||||||||
| Official Citation: | Low-level vibrational relaxation in single gas-surface encounters. Molecular structure, surface, and temperature effects V. T. Amorebieta and A. J. Colussi The Journal of Physical Chemistry 1984 88 (19), 4284-4287 DOI: 10.1021/j150663a019 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58540 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 24 Jun 2015 20:29 | |||||||||
| Last Modified: | 10 Nov 2021 22:06 |
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