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Thermochemistry of fluoroxy compounds: a linear correlation between O-F bond energies and ^(19)fluorine chemical shifts

Ghibaudi, E. and Colussi, A. J. (1984) Thermochemistry of fluoroxy compounds: a linear correlation between O-F bond energies and ^(19)fluorine chemical shifts. Inorganic Chemistry, 23 (6). pp. 635-636. ISSN 0020-1669. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154813784

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Abstract

The class of fluoroxy compounds ROF has been extensively investigated due to the peculiar chemical properties associated with the relatively weak O-F bond. They have also found generalized use as propellants and in the synthesis of organic and inorganic fluorinated species. In this communication it is shown that these compounds offer the rather unique example of a linear correlation between bond energies and NMR chemical shifts over wide ranges (13 kcal/mol and 100 ppm, respectively), which include the least and the most stable members of the family.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ic00174a001DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ic00174a001PublisherArticle
ORCID:
AuthorORCID
Colussi, A. J.0000-0002-3400-4101
Alternate Title:Thermochemistry of fluoroxy compounds: a linear correlation between oxygen-fluorine bond energies and fluorine-19 chemical shifts
Additional Information:© 1984 American Chemical Society. Received July 26, 1983.
Issue or Number:6
Record Number:CaltechAUTHORS:20150623-154813784
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150623-154813784
Official Citation:Thermochemistry of fluoroxy compounds: a linear correlation between oxygen-fluorine bond energies and fluorine-19 chemical shifts E. Ghibaudi and A. J. Colussi Inorganic Chemistry 1984 23 (6), 635-636 DOI: 10.1021/ic00174a001
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:58543
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:24 Jun 2015 20:02
Last Modified:03 Oct 2019 08:37

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