Ghibaudi, E. and Colussi, A. J. (1984) Thermochemistry of fluoroxy compounds: a linear correlation between O-F bond energies and ^(19)fluorine chemical shifts. Inorganic Chemistry, 23 (6). pp. 635-636. ISSN 0020-1669. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154813784
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Abstract
The class of fluoroxy compounds ROF has been extensively investigated due to the peculiar chemical properties associated with the relatively weak O-F bond. They have also found generalized use as propellants and in the synthesis of organic and inorganic fluorinated species. In this communication it is shown that these compounds offer the rather unique example of a linear correlation between bond energies and NMR chemical shifts over wide ranges (13 kcal/mol and 100 ppm, respectively), which include the least and the most stable members of the family.
| Item Type: | Article | |||||||||
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| Alternate Title: | Thermochemistry of fluoroxy compounds: a linear correlation between oxygen-fluorine bond energies and fluorine-19 chemical shifts | |||||||||
| Additional Information: | © 1984 American Chemical Society. Received July 26, 1983. | |||||||||
| Issue or Number: | 6 | |||||||||
| Record Number: | CaltechAUTHORS:20150623-154813784 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150623-154813784 | |||||||||
| Official Citation: | Thermochemistry of fluoroxy compounds: a linear correlation between oxygen-fluorine bond energies and fluorine-19 chemical shifts E. Ghibaudi and A. J. Colussi Inorganic Chemistry 1984 23 (6), 635-636 DOI: 10.1021/ic00174a001 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58543 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 24 Jun 2015 20:02 | |||||||||
| Last Modified: | 03 Oct 2019 08:37 |
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