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Temperature dependence of cage processes in the photofragmentation of phenyl acetate

Ghibaudi, E. and Colussi, A. J. (1983) Temperature dependence of cage processes in the photofragmentation of phenyl acetate. Chemical Physics Letters, 94 (1). pp. 121-125. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154814272

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Abstract

It was found that the ratio of initial yields of o-hydroxyacetophenone and phenol in the photodecomposition of phenyl acetate in hexane is a linear function of ηT^(1/2) between 224 and 330 K. The observed temperature dependence is ascribed to the competition between combination and disproportionation of acetyl and phenoxy radicals rather than to geminate combination and escape from the solvent cage.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0009-2614(83)87223-6DOIArticle
http://www.sciencedirect.com/science/article/pii/0009261483872236PublisherArticle
ORCID:
AuthorORCID
Colussi, A. J.0000-0002-3400-4101
Additional Information:© 1983 Elsevier. Received 4 October 1982. This work has been supported by a grant from Comisión de Investigaciones Científicas de la Provincia de Buenos Aires. Mr. E.F. Valla provided valuable technical assistance.
Funders:
Funding AgencyGrant Number
Comisión de Investigaciones Cientificas de la Provincia de Buenos AiresUNSPECIFIED
Issue or Number:1
Record Number:CaltechAUTHORS:20150623-154814272
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150623-154814272
Official Citation:E. Ghibaudi, A.J. Colussi, Temperature dependence of cage processes in the photofragmentation of phenyl acetate, Chemical Physics Letters, Volume 94, Issue 1, 7 January 1983, Pages 121-125, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(83)87223-6. (http://www.sciencedirect.com/science/article/pii/0009261483872236)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:58545
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:24 Jun 2015 20:16
Last Modified:03 Oct 2019 08:37

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