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ESR spectra of fluorine-containing radicals of phosphorus and arsenic

Boate, A. R. and Colussi, A. J. and Morton, J. R. and Preston, K. F. (1976) ESR spectra of fluorine-containing radicals of phosphorus and arsenic. Chemical Physics Letters, 37 (1). pp. 135-137. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20150623-154816726

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Abstract

ESR spectra observed at 120 K in γ-irradiated solid solutions of PF_5 in neopentane and AsF_5 in SF_6 are ascribed to the radical ions PF_5^− and AsF_5^− in which the unpaired electron interacts strongly with the central nucleus and with four equivalent ^(19)F nuclei. Hyperfine interaction with the fifth ^(19)F nucleus was not resolvable in either case. The spectra were quite distinct from those of the tetrafluorides PF_4 and AsF_4, thus eliminating the possibility that they were due to tetrafluoride radicals undergoing rapid intramolecular ^(19)F exchange.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0009-2614(76)80178-9DOIArticle
http://www.sciencedirect.com/science/article/pii/0009261476801789PublisherArticle
ORCID:
AuthorORCID
Colussi, A. J.0000-0002-3400-4101
Additional Information:© 1976 Elsevier. Received 22 July 1975.
Funders:
Funding AgencyGrant Number
National Research Council of CanadaUNSPECIFIED
Issue or Number:1
Record Number:CaltechAUTHORS:20150623-154816726
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150623-154816726
Official Citation:A.R. Boate, A.J. Colussi, J.R. Morton, K.F. Preston, ESR spectra of fluorine-containing radicals of phosphorus and arsenic, Chemical Physics Letters, Volume 37, Issue 1, 1 January 1976, Pages 135-137, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(76)80178-9. (http://www.sciencedirect.com/science/article/pii/0009261476801789)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:58554
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:24 Jun 2015 17:36
Last Modified:03 Oct 2019 08:37

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