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Unimolecular reactions at low energies and RRKM behavior: isomerization and dissociation

Khundkar, L. R. and Marcus, R. A. and Zewail, A. H. (1983) Unimolecular reactions at low energies and RRKM behavior: isomerization and dissociation. Journal of Physical Chemistry, 87 (14). pp. 2473-2476. ISSN 0022-3654. https://resolver.caltech.edu/CaltechAUTHORS:20150624-095555455

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Abstract

Rates of isomerization of electronically excited trans-stilbene and of the dissociation of isoquinoline-solvent complexes in jet beams are compared with those expected from RRKM theory as a function of energy; the comparison is made at low vibrational energies (~1200-3000 cm^(-1)). The jet result for the threshold energy of the isomerization is compared with the activation energy for the reaction in solution. The two values are in good agreement.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/j100237a008 DOIArticle
http://pubs.acs.org/doi/abs/10.1021/j100237a008PublisherArticle
ORCID:
AuthorORCID
Marcus, R. A.0000-0001-6547-1469
Additional Information:© 1983 American Chemical Society. Received: April 18, 1983. It is a pleasure to acknowledge the support of this work by the National Science Foundation. L.R.K. is grateful to the Exxon Educational Foundation for a graduate fellowship during the course of this work.
Funders:
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NSFUNSPECIFIED
Exxon Educational FoundationUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Arthur Amos Noyes Laboratory of Chemical Physics6826
Issue or Number:14
Record Number:CaltechAUTHORS:20150624-095555455
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150624-095555455
Official Citation:Unimolecular reactions at low energies and RRKM behavior: isomerization and dissociation L. R. Khundkar, R. A. Marcus, and A. H. Zewail The Journal of Physical Chemistry 1983 87 (14), 2473-2476 DOI: 10.1021/j100237a008
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:58578
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:24 Jun 2015 17:06
Last Modified:22 Nov 2019 09:58

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