Voth, Gregory A. and Marcus, R. A. (1985) Semiclassical Dressed State Theory for the Vibrational Excitation of a Morse Oscillator by Radiation. Journal of Physical Chemistry, 89 (11). pp. 2208-2213. ISSN 0022-3654. doi:10.1021/j100257a015. https://resolver.caltech.edu/CaltechAUTHORS:20150629-101153293
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Abstract
A uniform semiclassical theory is developed to treat the interaction of a Morse oscillator with a monochromatic radiation field. The correspondence with quantum-mechanical dressed state theory for the Rabi and resonant excitation frequencies is demonstrated, and the semiclassical theory is used to describe resonant one- and two-photon absorption processes. The results are extended to state-to-state vibrational excitation in a polyatomic species.
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| Additional Information: | © 1985 American Chemical Society. Received: September 28, 1984. This work has been supported by a grant from the National Science Foundation. | |||||||||
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| Issue or Number: | 11 | |||||||||
| DOI: | 10.1021/j100257a015 | |||||||||
| Record Number: | CaltechAUTHORS:20150629-101153293 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150629-101153293 | |||||||||
| Official Citation: | Semiclassical dressed state theory for the vibrational excitation of a Morse oscillator by radiation Gregory A. Voth and R. A. Marcus The Journal of Physical Chemistry 1985 89 (11), 2208-2213 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58660 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Jason Perez | |||||||||
| Deposited On: | 29 Jun 2015 20:00 | |||||||||
| Last Modified: | 10 Nov 2021 22:08 |
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