Nadler, W. and Marcus, R. A. (1988) Non-exponential time behavior of electron transfer in an inhomogeneous polar medium. Chemical Physics Letters, 144 (1). pp. 24-30. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20150629-121821767
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Abstract
An analysis is made of electron transfer (ET) in a polar medium described by a distribution of dielectric relaxation times, for the case that intramolecular contributions to the ET are negligible. The generalized moment expansion is used for an approximate multi-exponential description of the non-exponential time behavior of the ET. As an example, ET in glycerol-like solvents is considered, treated by the spatially inhomogeneous model for dielectric relaxation. For this model the ET rate at long times is found to vary as τ_0^(−1), τ_0 being a dielectric relaxation time parameter, in contrast with a fractional dependence at short times.
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| Additional Information: | © 1988 Elsevier Science Publishers B.V. (North-Holland Physics Publishing Division). Received 19 October 1987; in final form 4 December 1987. Available online 29 January 2002. It is a pleasure to acknowledge the support of this research by the National Science Foundation and the Office of Naval Research. | |||||||||
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| Issue or Number: | 1 | |||||||||
| Record Number: | CaltechAUTHORS:20150629-121821767 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150629-121821767 | |||||||||
| Official Citation: | W. Nadler, R.A. Marcus, Non-exponential time behavior of electron transfer in an inhomogeneous polar medium, Chemical Physics Letters, Volume 144, Issue 1, 12 February 1988, Pages 24-30, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(88)87083-0. (http://www.sciencedirect.com/science/article/pii/0009261488870830) | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58671 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 29 Jun 2015 20:03 | |||||||||
| Last Modified: | 22 Nov 2019 09:58 |
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