Wardlaw, David M. and Marcus, R. A. (1988) On the Statistical Theory of Unimolecular Processes. In: Evolution of Size Effects in Chemical Dynamics. Advances in Chemical Physics. No.70. Wiley , Hoboken, NJ, pp. 231-263. ISBN 978-0-470-14179-3. https://resolver.caltech.edu/CaltechAUTHORS:20150629-145635893
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20150629-145635893
Abstract
In recent years there has been an increasing use of laser spectroscopic and other techniques to investigate unimolecular dissociations of molecules, both to initiate a dissociation and to measure the formation of the individual quantum states of the immediate reaction products. This chapter is concerned with a description of statistical theories used to calculate the rates of such dissociations, for example, of a molecule AB, AB → A + B, and to calculate the distribution of the quantum states of the fragments A and B.
Item Type: | Book Section | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
Related URLs: |
| |||||||||
ORCID: |
| |||||||||
Additional Information: | © 1988 by John Wiley & Sons, Inc. Published Online: 14 Mar 2007. NSERC of Canada University Research Fellow. It is a pleasure to acknowledge the support of this research by the Natural Sciences and Engineering Research Council of Canada (D.M.W.) and by the National Science Foundation (R.A.M.). | |||||||||
Funders: |
| |||||||||
Subject Keywords: | RRKM theory; angular momentum conservation; CH_3 recombination; NCNO dissociation; H_2CO dissociation | |||||||||
Other Numbering System: |
| |||||||||
Series Name: | Advances in Chemical Physics | |||||||||
Issue or Number: | 70 | |||||||||
DOI: | 10.1002/9780470141199.ch7 | |||||||||
Record Number: | CaltechAUTHORS:20150629-145635893 | |||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150629-145635893 | |||||||||
Official Citation: | Wardlaw, D. M. and Marcus, R. A. (1988) On the Statistical Theory of Unimolecular Processes, in Advances in Chemical Physics: Evolution of Size Effects in Chemical Dynamics Part 1, Volume 70 (eds I. Prigogine and S. A. Rice), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470141199.ch7 | |||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
ID Code: | 58682 | |||||||||
Collection: | CaltechAUTHORS | |||||||||
Deposited By: | Ruth Sustaita | |||||||||
Deposited On: | 30 Jun 2015 13:57 | |||||||||
Last Modified: | 10 Nov 2021 22:09 |
Repository Staff Only: item control page