Wardlaw, David M. and Marcus, R. A. (1988) On the Statistical Theory of Unimolecular Processes. In: Evolution of Size Effects in Chemical Dynamics. Advances in Chemical Physics. No.70. Wiley , Hoboken, NJ, pp. 231-263. ISBN 978-0-470-14179-3. http://resolver.caltech.edu/CaltechAUTHORS:20150629-145635893
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Abstract
In recent years there has been an increasing use of laser spectroscopic and other techniques to investigate unimolecular dissociations of molecules, both to initiate a dissociation and to measure the formation of the individual quantum states of the immediate reaction products. This chapter is concerned with a description of statistical theories used to calculate the rates of such dissociations, for example, of a molecule AB, AB → A + B, and to calculate the distribution of the quantum states of the fragments A and B.
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| Additional Information: | © 1988 by John Wiley & Sons, Inc. Published Online: 14 Mar 2007. NSERC of Canada University Research Fellow. It is a pleasure to acknowledge the support of this research by the Natural Sciences and Engineering Research Council of Canada (D.M.W.) and by the National Science Foundation (R.A.M.). | |||||||||
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| Subject Keywords: | RRKM theory; angular momentum conservation; CH_3 recombination; NCNO dissociation; H_2CO dissociation | |||||||||
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| Record Number: | CaltechAUTHORS:20150629-145635893 | |||||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20150629-145635893 | |||||||||
| Official Citation: | Wardlaw, D. M. and Marcus, R. A. (1988) On the Statistical Theory of Unimolecular Processes, in Advances in Chemical Physics: Evolution of Size Effects in Chemical Dynamics Part 1, Volume 70 (eds I. Prigogine and S. A. Rice), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470141199.ch7 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58682 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 30 Jun 2015 13:57 | |||||||||
| Last Modified: | 30 Jun 2015 13:57 |
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