Marcus, R. A. (1987) Solvent Dynamical and Symmetrized Potential Aspects of Electron Transfer Rates. In: Understanding Molecular Properties. Springer , Dordrecht, pp. 229-236. ISBN 978-94-010-8182-5. https://resolver.caltech.edu/CaltechAUTHORS:20150630-094059392
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Abstract
Recent experiments on very fast electron transfers have provided evidence for slow solvent dynamics under such conditions. The role of the vibrational motion of the reactants is included in the present treatment. The overall decay can be single- or multi-exponential. A simple approximate expression is given for a characteristic reaction time. The “symmetrization” approximation in the cross-relation is also discussed.
| Item Type: | Book Section | |||||||||
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| Additional Information: | © 1987 by D. Reidel Publishing Company. The support of this research by the National Science Foundation is gratefully acknowledged. Carl and Ingrid, we salute you, and extend our very best wishes for the future. | |||||||||
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| DOI: | 10.1007/978-94-009-3781-9_13 | |||||||||
| Record Number: | CaltechAUTHORS:20150630-094059392 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150630-094059392 | |||||||||
| Official Citation: | Solvent Dynamical and Symmetrized Potential Aspects of Electron Transfer Rates R. A. Marcus Pages 229-236 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58696 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 30 Jun 2015 17:01 | |||||||||
| Last Modified: | 10 Nov 2021 22:09 |
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