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Solvent Dynamical and Symmetrized Potential Aspects of Electron Transfer Rates

Marcus, R. A. (1987) Solvent Dynamical and Symmetrized Potential Aspects of Electron Transfer Rates. In: Understanding Molecular Properties. Springer , Dordrecht, pp. 229-236. ISBN 978-94-010-8182-5. https://resolver.caltech.edu/CaltechAUTHORS:20150630-094059392

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Abstract

Recent experiments on very fast electron transfers have provided evidence for slow solvent dynamics under such conditions. The role of the vibrational motion of the reactants is included in the present treatment. The overall decay can be single- or multi-exponential. A simple approximate expression is given for a characteristic reaction time. The “symmetrization” approximation in the cross-relation is also discussed.


Item Type:Book Section
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1007/978-94-009-3781-9_13DOIArticle
http://link.springer.com/chapter/10.1007%2F978-94-009-3781-9_13PublisherArticle
ORCID:
AuthorORCID
Marcus, R. A.0000-0001-6547-1469
Additional Information:© 1987 by D. Reidel Publishing Company. The support of this research by the National Science Foundation is gratefully acknowledged. Carl and Ingrid, we salute you, and extend our very best wishes for the future.
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NSFUNSPECIFIED
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Caltech Noyes Laboratory of Chemical Physics7396
Record Number:CaltechAUTHORS:20150630-094059392
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150630-094059392
Official Citation: Solvent Dynamical and Symmetrized Potential Aspects of Electron Transfer Rates R. A. Marcus Pages 229-236
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:58696
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:30 Jun 2015 17:01
Last Modified:22 Nov 2019 09:58

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