Marcus, R. A. (1985) Aspects of Intramolecular Dynamics in Chemistry. In: Chaotic Behavior in Quantum Systems. NATO ASI series. Series B, Physics. No.120. Springer , New York, NY, pp. 293-298. ISBN 978-1-4612-9485-6. https://resolver.caltech.edu/CaltechAUTHORS:20150701-082708661
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Abstract
The role of chaotic and quasiperiodic behavior of isolated molecules is discussed. The quantum analog of classical quasi- periodic states appears to be relatively well understood. A possible quantum analog of classical chaotic behavior is described, using overlapping quantum mechanical Fermi resonances as a way of generating irregularities. The relation of these Fermi resonances to avoided crossings in eigenvalue plots and to various treatments of intramolecular dynamics in the chemical literature is outlined.
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| Additional Information: | © 1985 Springer International Publishing. It is a pleasure to acknowledge the support of this research by a grant from the National Science Foundation. Contribution No. 6894 from the California Institute of Technology. | |||||||||
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| Series Name: | NATO ASI series. Series B, Physics | |||||||||
| Issue or Number: | 120 | |||||||||
| DOI: | 10.1007/978-1-4613-2443-0_19 | |||||||||
| Record Number: | CaltechAUTHORS:20150701-082708661 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150701-082708661 | |||||||||
| Official Citation: | Aspects of Intramolecular Dynamics in Chemistry R. A. Marcus Pages 293-298 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58726 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 01 Jul 2015 16:04 | |||||||||
| Last Modified: | 10 Nov 2021 22:09 |
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