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Further Developments in Electron Transfer

Marcus, R. A. and Siders, Paul (1982) Further Developments in Electron Transfer. In: Mechanistic Aspects of Inorganic Reactions. ACS Symposium Series. No.198. American Chemical Society , Washington, DC, pp. 235-253. ISBN 9780841207349. http://resolver.caltech.edu/CaltechAUTHORS:20150701-132931351

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Abstract

The inverted region in electron transfer reactions is studied for the reaction of electronically-excited ruthenium(II) tris-bipyridyl ions with various metal(III) tris-bipyridyl complexes. Numerical calculations for the diffusion-reaction equation are summarized for the case where electron transfer occurs over a range of distances. Comparison is made with the experimental data and with a simple approximation. The analysis reveals some of the factors which can cause a flattening of the ln k_(obs) versus ΔG^O curve in the inverted region. Ways of improving the chance of observing the effect are discussed.


Item Type:Book Section
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http://dx.doi.org/10.1021/bk-1982-0198.ch010DOIArticle
http://pubs.acs.org/doi/abs/10.1021/bk-1982-0198.ch010PublisherArticle
Additional Information:© 1982 American Chemical Society. Received April 21, 1982. Publication Date (Print): July 23, 2009. It is a pleasure to acknowledge support of this research by a grant from the National Science Foundation. Contribution No. 6494 from the California Institute of Technology.
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Caltech Arthur Amos Noyes Laboratory of Chemical Physics6494
Record Number:CaltechAUTHORS:20150701-132931351
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150701-132931351
Official Citation:Further Developments in Electron Transfer R. A. MARCUS and PAUL SIDERS Mechanistic Aspects of Inorganic Reactions. September 27, 1982, 235-253 Doi:10.1021/bk-1982-0198.ch010
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:58738
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:01 Jul 2015 20:57
Last Modified:01 Jul 2015 20:57

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