Marcus, R. A. and Siders, Paul (1982) Further Developments in Electron Transfer. In: Mechanistic Aspects of Inorganic Reactions. ACS Symposium Series. No.198. American Chemical Society , Washington, DC, pp. 235-253. ISBN 9780841207349. https://resolver.caltech.edu/CaltechAUTHORS:20150701-132931351
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Abstract
The inverted region in electron transfer reactions is studied for the reaction of electronically-excited ruthenium(II) tris-bipyridyl ions with various metal(III) tris-bipyridyl complexes. Numerical calculations for the diffusion-reaction equation are summarized for the case where electron transfer occurs over a range of distances. Comparison is made with the experimental data and with a simple approximation. The analysis reveals some of the factors which can cause a flattening of the ln k_(obs) versus ΔG^O curve in the inverted region. Ways of improving the chance of observing the effect are discussed.
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| Additional Information: | © 1982 American Chemical Society. Received April 21, 1982. Publication Date (Print): July 23, 2009. It is a pleasure to acknowledge support of this research by a grant from the National Science Foundation. Contribution No. 6494 from the California Institute of Technology. | |||||||||
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| Series Name: | ACS Symposium Series | |||||||||
| Issue or Number: | 198 | |||||||||
| DOI: | 10.1021/bk-1982-0198.ch010 | |||||||||
| Record Number: | CaltechAUTHORS:20150701-132931351 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150701-132931351 | |||||||||
| Official Citation: | Further Developments in Electron Transfer R. A. MARCUS and PAUL SIDERS Mechanistic Aspects of Inorganic Reactions. September 27, 1982, 235-253 Doi:10.1021/bk-1982-0198.ch010 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 58738 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 01 Jul 2015 20:57 | |||||||||
| Last Modified: | 10 Nov 2021 22:09 |
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