Holtz, David and Beauchamp, J. L. (1971) Xenon as a Nucleophile in Gas-Phase Displacement Reactions: Formation of the Methyl Xenonium Ion. Science, 173 (4003). pp. 1237-1238. ISSN 0036-8075. doi:10.1126/science.173.4003.1237. https://resolver.caltech.edu/CaltechAUTHORS:20150729-081841016
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Abstract
Xenon undergoes reaction with protonated methyl fluoride in the gas phase to form abundant quantities of the stable methyl xenonium ion, CH_3Xe^+. Estimated values for the xenon-carbon and krypton-carbon bond strengths in the rare gas-methyl molecular ions are 43 ± 8 and 21 ± 15 kilocalories per mole, respectively.
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| Additional Information: | © 1971 American Association for the Advancement of Science. Received 7 June 1971. Work supported in part by the U.S. Atomic Energy Commission under grant AT(04-3)67-8. Contribution No. 4328 from the California Institute of Technology. | |||||||||
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| Issue or Number: | 4003 | |||||||||
| DOI: | 10.1126/science.173.4003.1237 | |||||||||
| Record Number: | CaltechAUTHORS:20150729-081841016 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150729-081841016 | |||||||||
| Official Citation: | Xenon as a Nucleophile in Gas-Phase Displacement Reactions: Formation of the Methyl Xenonium Ion David Holtz and J. L. Beauchamp Science 24 September 1971: 173 (4003), 1237-1238. [DOI:10.1126/science.173.4003.1237] | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 59047 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 29 Jul 2015 16:32 | |||||||||
| Last Modified: | 10 Nov 2021 22:14 |
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