Quiroga, S. L. and Mendiara, S. and Colussi, A. J. (1987) Ammonia from power plant emission gases via reduction of the nitrosyl complex de Fe(II)EDTA by S(IV). Anales de la Asociación Química Argentina, 75 (3). pp. 333-338. ISSN 0365-0375. https://resolver.caltech.edu/CaltechAUTHORS:20150804-125127073
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Abstract
The full reduction of nitric oxide in nitrosyl complexes of Fe{Il)EDTA by aqueous bisulfite solutions has been investigated under a variety of conditions. It was found that about 85 % of the initial NO is converted into NH_4 by prior incubation of FeEDTA(NO)^(2-) in excess bisulfite at 300 K, pH = 6.8 during 4 hours, followed by a second stage in which the reaction mixture is brought to 373 K, pH= 1 for 6 hours. Partial oxidation of the metal center reveals an active role for FeEDTA^(2-) in this process.
| Item Type: | Article | ||||
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| Additional Information: | © 1987 Asociación Química Argentina. | ||||
| Issue or Number: | 3 | ||||
| Record Number: | CaltechAUTHORS:20150804-125127073 | ||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150804-125127073 | ||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||
| ID Code: | 59186 | ||||
| Collection: | CaltechAUTHORS | ||||
| Deposited By: | George Porter | ||||
| Deposited On: | 07 Aug 2015 22:52 | ||||
| Last Modified: | 03 Oct 2019 08:44 |
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