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Gas/Particle Partitioning and Secondary Organic Aerosol Yields

Odum, Jay R. and Hoffmann, Thorsten and Bowman, Frank and Collins, Don and Flagan, Richard C. and Seinfeld, John H. (1996) Gas/Particle Partitioning and Secondary Organic Aerosol Yields. Environmental Science and Technology, 30 (8). pp. 2580-2585. ISSN 0013-936X. https://resolver.caltech.edu/CaltechAUTHORS:20150805-113921105

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Abstract

Secondary organic aerosol (SOA) formation is considered in the framework of the gas/particle partitioning absorption model outlined by Pankow. Expressions for the fractional SOA yield (Y) are developed within this framework and shown to be a function of the organic aerosol mass concentration, M_o. These expressions are applied to over 30 individual reactive organic gas (ROG) photooxidation smog chamber experiments. Analysis of the data from these experiments clearly shows that Y is a strong function of M_o and that secondary organic aerosol formation is best described by a gas/particle partitioning absorption model. In addition to the 30 individual ROG experiments, three experiments were performed with ROG mixtures. The expressions developed for Y in terms of M_o, used in conjunction with the overall yield data from the individual ROG experiments, are able to account for the M_o generated in the ROG mixture experiments. This observation not only suggests that SOA yields for individual ROGs are additive but that smog chamber SOA yield data may be confidently extrapolated to the atmosphere in order to determine the important ambient sources of SOA in the environment.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/es950943+DOIArticle
http://pubs.acs.org/doi/abs/10.1021/es950943+PublisherArticle
ORCID:
AuthorORCID
Flagan, Richard C.0000-0001-5690-770X
Seinfeld, John H.0000-0003-1344-4068
Additional Information:© 1996 American Chemical Society. Received for review December 18, 1995. Revised manuscript received April 1 7, 1996. Accepted April 19, 1996. This work was supported by the U.S. Environmental Protection Agency Exploratory Environmental Research Center on Airborne Organics (R-819714-01-0), the National Science Foundation Grant ATM-9307603, the Coordinating Research Council (A-5-1), and the Chevron Corporation.
Funders:
Funding AgencyGrant Number
Environmental Protection Agency (EPA)R-819714-01-0
NSFATM-9307603
Coordinating Research CouncilA-5-1
Chevron CorporationUNSPECIFIED
Issue or Number:8
Record Number:CaltechAUTHORS:20150805-113921105
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150805-113921105
Official Citation:Gas/Particle Partitioning and Secondary Organic Aerosol Yields Jay R. Odum, Thorsten Hoffmann, Frank Bowman, Don Collins, Richard C. Flagan, and John H. Seinfeld Environmental Science & Technology 1996 30 (8), 2580-2585 DOI: 10.1021/es950943+
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:59240
Collection:CaltechAUTHORS
Deposited By: Irina Meininger
Deposited On:06 Aug 2015 20:24
Last Modified:03 Oct 2019 08:44

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