Levison, S. A. and Marcus, R. A. (1968) Kinetics of ferrocyanide reduction of quinones. Journal of Physical Chemistry, 72 (1). pp. 358-360. ISSN 0022-3654. doi:10.1021/j100847a071. https://resolver.caltech.edu/CaltechAUTHORS:20150812-165217873
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Abstract
We describe here the kinetics of ferrocyanide reduction of 2,5-dichloro-, benzo-, and 2,5-dimethylquinones (denoted below by I, II, III) in 1 M KCl. Reagent materials were used where available and the hydroquinones of I and III were synthesized by SnCl_2 reduction and recrystallization. Slightly alcoholic solutions of quinone in 1 M KCl were deoxygenated, placed in blackened vessels at 27°, and then in a 10-cm path Beckman cell. Buffered 1 M KCl ferrocyanide at 27° was added and the rate was measured from ferrocyanide disappearance at 420 mµ or disappearance of I at 275 mµ, using a Beckman.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1968 American Chemical Society. (Received July 10, 1967) | |||||||||
| Issue or Number: | 1 | |||||||||
| DOI: | 10.1021/j100847a071 | |||||||||
| Record Number: | CaltechAUTHORS:20150812-165217873 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150812-165217873 | |||||||||
| Official Citation: | Kinetics of ferrocyanide reduction of quinones Stuart A. Levison and Rudolph A. Marcus The Journal of Physical Chemistry 1968 72 (1), 358-360 DOI: 10.1021/j100847a071 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 59470 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 13 Aug 2015 19:34 | |||||||||
| Last Modified: | 10 Nov 2021 22:21 |
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