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Analytical mechanics and almost vibrationally-adiabatic chemical reactions

Marcus, R. A. (1967) Analytical mechanics and almost vibrationally-adiabatic chemical reactions. Discussions of the Faraday Society, 44 . pp. 7-13. ISSN 0366-9033.

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Co-ordinates and "vibrationally-adiabatic" approximations are described for reactions in three dimensions. Some reactions may demonstrate a fairly strict adiabaticity for certain degrees of freedom and a statistical adiabaticity for others. Some will simply be strongly vibrationally-nonadiabatic. Several topics in kinetics are considered from the viewpoint of vibrational-adiabaticity or mild non-adiabaticity

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Marcus, R. A.0000-0001-6547-1469
Additional Information:© 1967 Royal Society of Chemistry. Received 14th June 1967. Acknowledgement is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, and to the National Science Foundation, for their support of this research.
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American Chemical Society Petroleum Research FundUNSPECIFIED
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Official Citation:Analytical mechanics and almost vibrationally-adiabatic chemical reactions R. A. Marcus Discuss. Faraday Soc., 1967,44, 7-13 DOI: 10.1039/DF9674400007
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:59511
Deposited By: George Porter
Deposited On:13 Aug 2015 23:07
Last Modified:22 Nov 2019 09:58

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