Marcus, R. A. (1969) Unusual slopes of free energy plots in kinetics. Journal of the American Chemical Society, 91 (26). pp. 7224-7225. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20150817-154034498
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Abstract
Theoretical equations are used to comment on the relation between the slope of activation free energy-standard free energy of reaction plots and the concept of the position of the transition state along the reaction coordinate. The equations are then used to consider some recent experimental findings of unusual Brønsted coefficients.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1969 American Chemical Society. Received April 1, 1969. Acknowledgment is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, and to the National Science Foundation for their support of this research. | |||||||||
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| Issue or Number: | 26 | |||||||||
| Record Number: | CaltechAUTHORS:20150817-154034498 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150817-154034498 | |||||||||
| Official Citation: | Unusual slopes of free energy plots in kinetics Rudolph A. Marcus Journal of the American Chemical Society 1969 91 (26), 7224-7225 DOI: 10.1021/ja01054a003 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 59662 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 18 Aug 2015 15:13 | |||||||||
| Last Modified: | 22 Nov 2019 09:58 |
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