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Unusual slopes of free energy plots in kinetics

Marcus, R. A. (1969) Unusual slopes of free energy plots in kinetics. Journal of the American Chemical Society, 91 (26). pp. 7224-7225. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20150817-154034498

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Abstract

Theoretical equations are used to comment on the relation between the slope of activation free energy-standard free energy of reaction plots and the concept of the position of the transition state along the reaction coordinate. The equations are then used to consider some recent experimental findings of unusual Brønsted coefficients.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01054a003DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01054a003PublisherArticle
ORCID:
AuthorORCID
Marcus, R. A.0000-0001-6547-1469
Additional Information:© 1969 American Chemical Society. Received April 1, 1969. Acknowledgment is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, and to the National Science Foundation for their support of this research.
Funders:
Funding AgencyGrant Number
American Chemical Society Petroleum Research FundUNSPECIFIED
NSFUNSPECIFIED
Issue or Number:26
Record Number:CaltechAUTHORS:20150817-154034498
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150817-154034498
Official Citation:Unusual slopes of free energy plots in kinetics Rudolph A. Marcus Journal of the American Chemical Society 1969 91 (26), 7224-7225 DOI: 10.1021/ja01054a003
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:59662
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:18 Aug 2015 15:13
Last Modified:22 Nov 2019 09:58

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