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Secondary deuterium isotope effects in solvolyses of small-ring compounds

Nikoletić, Marija and Borčić, Stanko and Sunko, Dionis E. (1964) Secondary deuterium isotope effects in solvolyses of small-ring compounds. Proceedings of the National Academy of Sciences of the United States of America, 52 (4). pp. 893-896. ISSN 0027-8424. PMCID PMC300368. https://resolver.caltech.edu/CaltechAUTHORS:20150817-155928801

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Abstract

The importance of nonclassical ions as relatively stable intermediates in SN1- type reactions is a matter of considerable current controversy. A very important question in this controversy is the extent to which the observed rate accelerations are due to nonclassical electron delocalization in the transition states as compared to high initial state free energies because of steric strain.


Item Type:Article
Related URLs:
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http://www.pnas.org/content/52/4/893.full.pdfPublisherArticle
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC300368/PubMed CentralArticle
http://www.jstor.org/stable/72381JSTORArticle
Additional Information:© 1964 National Academy of Sciences. Communicated by John D. Roberts, August 31, 1964. Taken in part from the Ph.D. thesis of M. N., University of Zagreb, 1963.
Issue or Number:4
PubMed Central ID:PMC300368
Record Number:CaltechAUTHORS:20150817-155928801
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150817-155928801
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:59667
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:18 Aug 2015 15:06
Last Modified:03 Oct 2019 08:49

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