Nikoletić, Marija and Borčić, Stanko and Sunko, Dionis E. (1964) Secondary deuterium isotope effects in solvolyses of small-ring compounds. Proceedings of the National Academy of Sciences of the United States of America, 52 (4). pp. 893-896. ISSN 0027-8424. PMCID PMC300368. https://resolver.caltech.edu/CaltechAUTHORS:20150817-155928801
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Abstract
The importance of nonclassical ions as relatively stable intermediates in SN1- type reactions is a matter of considerable current controversy. A very important question in this controversy is the extent to which the observed rate accelerations are due to nonclassical electron delocalization in the transition states as compared to high initial state free energies because of steric strain.
| Item Type: | Article | ||||||||||||
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| Additional Information: | © 1964 National Academy of Sciences. Communicated by John D. Roberts, August 31, 1964. Taken in part from the Ph.D. thesis of M. N., University of Zagreb, 1963. | ||||||||||||
| Issue or Number: | 4 | ||||||||||||
| PubMed Central ID: | PMC300368 | ||||||||||||
| Record Number: | CaltechAUTHORS:20150817-155928801 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150817-155928801 | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 59667 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | George Porter | ||||||||||||
| Deposited On: | 18 Aug 2015 15:06 | ||||||||||||
| Last Modified: | 03 Oct 2019 08:49 |
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