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The occurrence of bisulfite-aldehyde addition products in fog- and cloudwater

Munger, J. W. and Jacob, D. J. and Hoffmann, M. R. (1984) The occurrence of bisulfite-aldehyde addition products in fog- and cloudwater. Journal of Atmospheric Chemistry, 1 (4). pp. 335-350. ISSN 0167-7764. https://resolver.caltech.edu/CaltechAUTHORS:20150818-100955783

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Abstract

Elevated concentrations of S(IV) and formaldehyde were observed in fog- and cloudwater at sites in California. The highest concentrations (up to 3 mM S(IV) and 0.7 mM CH_2O) were measured at Bakersfield, during a prolonged period of repeated fog. In Bakersfield [S(IV)] generally exceeded [CH_2O], while in the Los Angeles area the reverse was observed. The lowest concentrations of both species were observed at marine and high altitude sites away from local emissions. Equilibrium computations indicate that high concentrations of S(IV) cannot be achieved without the formation of S(IV)-RCHO adducts.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1007/BF00053799DOIArticle
http://link.springer.com/article/10.1007/BF00053799PublisherArticle
ORCID:
AuthorORCID
Hoffmann, M. R.0000-0002-0432-6564
Additional Information:© 1984 Reidel Publishing Company. Received: 24 October 1983; in revised form: 7 February 1984. This research was supported by the California Air Resources Board (Contract A2-048-32). We thank the CARB, the South Coast Air Quality Management District, the Los Angeles County Fire Department Forestry Division, the United States Navy, the National Park Service, and the Mt. Wilson Observatories for logistical support and the use of field facilities. We also thank J. Waldman and S. Boyce for their contributions to the success of this project.
Funders:
Funding AgencyGrant Number
California Air Resources Board (CARB)A2-048-32
Subject Keywords:Formaldehyde, sulfur (IV), sulfonic acids, sulfur oxidation, air pollution, fogwater chemistry
Issue or Number:4
Record Number:CaltechAUTHORS:20150818-100955783
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150818-100955783
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:59694
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:18 Aug 2015 18:34
Last Modified:03 Oct 2019 08:49

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