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Modeling and Characterization of a Particle-into-Liquid Sampler (PILS)

Sorooshian, Armin and Brechtel, Fred J. and Ma, Yilin and Weber, Rodney J. and Corless, Andrew and Flagan, Richard C. and Seinfeld, John H. (2006) Modeling and Characterization of a Particle-into-Liquid Sampler (PILS). Aerosol Science and Technology, 40 (6). pp. 396-409. ISSN 0278-6826. https://resolver.caltech.edu/CaltechAUTHORS:20150818-105347712

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Abstract

A modified particle-into-liquid sampler (PILS), based on the original design of Weber et al. (2001), is presented. The principal modification in this design is that collected liquid sample is delivered to vials held on a rotating carousel as opposed to an on-line analytical detector. A model is developed to predict aerosol mass concentrations measured by a PILS based on operating parameters and characteristics of the sampled aerosol. A backward model predicts the concentrations of the sampled aerosol based on operating parameters and concentrations measured by the PILS. Both models, which consider plumbing transmission efficiencies, droplet growth, mixing effects, and volatilization losses, predict mass concentrations that are consistent with laboratory tests for step changes in concentration. The average collection efficiency for species (Na^+, K^+, SO_4^(2−), Cl^−, NO_3^−) from a variety of aerosols compared to simultaneous measurements with a differential mobility analyzer (DMA) exceeded 96% except for NH_4^+ (88%); NH_4^+ is theoretically shown to be the most vulnerable to volatilization, followed by Cl^- and then NO_3^− , with greater losses caused by increasing droplet pH and temperature. The characterization tests highlight the importance of reducing NH_4^+ volatilization by keeping a stable tip temperature of 100°C at the point where steam and ambient air mix in the condensation chamber. Maintaining a stable tip temperature also avoids fluctuations in supersaturations that lead to increased deposition losses of larger droplets. Sample data from the 2004 International Consortium for Atmospheric Research on Transport and Transformation (ICARTT) field campaign are presented.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1080/02786820600632282DOIArticle
http://www.tandfonline.com/doi/abs/10.1080/02786820600632282PublisherArticle
ORCID:
AuthorORCID
Sorooshian, Armin0000-0002-2243-2264
Flagan, Richard C.0000-0001-5690-770X
Seinfeld, John H.0000-0003-1344-4068
Additional Information:© 2006 American Association for Aerosol Research. Received 16 December 2005; accepted 13 February 2006. This work was supported by the National Science Foundation grant ATM-0340832 and the Office of Naval Research.
Funders:
Funding AgencyGrant Number
NSFATM-0340832
Office of Naval Research (ONR)UNSPECIFIED
Issue or Number:6
Record Number:CaltechAUTHORS:20150818-105347712
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150818-105347712
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:59719
Collection:CaltechAUTHORS
Deposited By: Irina Meininger
Deposited On:19 Aug 2015 22:17
Last Modified:03 Oct 2019 08:49

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