Table 4. Molecular Weights Associated With Other Terpenes Detected by PTR-MS Compound m/z (mass + 1) Structure Description methyl chavicol 149a, 150 C10H12OH+ oxygenated terpene and isotope 65, 71, 73, 75, 85, 89, 97, 99, 101, 103, 109 b, 113, 121, 123c*, 124d, 125, 129, 131, 137, 151*, 153, 163, 165, 168d, 170d, 182d unidentified oxidation products verbenone 109, 110, 123, 133, 151, 152 C10H14OH+ oxygenated terpene, fragments, and isotopes 69, 71, 73, 75, 77, 83, 85, 87, 89, 93, 94, 97, 99, 100, 101, 107, 111*, 113*, 115, 123*, 124, 125, 127, 129, 130, 141*, 143, 144, 145, 151*, 152, 153, 159*, 167, 169*, 185, 230d unidentified oxidation products linalool 81, 82, 137, 138, 155, 156, C10H18OH+, C10H16H+ oxygenated terpene, fragments, and isotopes 60, 69, 71, 72, 73, 74, 75, 77, 79, 83, 85, 87, 89 ,93, 97, 99, 101, 107, 111*, 113*, 115, 123*, 124, 125, 127, 129, 141*, 143, 145, 151*, 153, 159*, 167, 169*, 185, 187, 188d unidentified oxidation products isoprene 69, 70 C5H8H+ isoprene and isotope 71, 72 C4H6OH+ MVK + MACR 83, 84 C5H6OH+ 3-methyl furan 57, 63, 65, 73, 75, 77, 79, 85, 86, 87, 89, 97, 99, 101, 103, 105, 113*, 115, 117, 129, 133 unidentified oxidation products aIons associated with parent terpenes listed in bold font represent ions > 20% of the unfragmented parent terpene. bUnidentified oxidation products in bold font are ions with > 5% yield (on a mole basis) from the parent terpene. cUnidentified oxidation products with asterisks represent ions that were observed in the canopy air of a coniferous forest in California by PTR-MS [Holzinger et al., 2005]. dEven mass-to-charge ratio oxidation products that are not carbon isotopes of other oxidation products are likely gas-phase nitrogen containing products, e.g., organic nitrates.