Table 6. Gas-Phase Yields From Terpene Photooxidation Experiments Terpene a CH2Ob % Yield C2H4O % Yield CH2O2 % Yield C3H6O % Yield C2H4O2 % Yield UnIDc % Yield Total C Balance,d % beta-caryophyllene 1.3 42 +/- 10 0.6 +/- 0.2 6.2 +/- 2 1.5 +/- 0.4 8.7 +/- 2 22 +/- 1 62 +/- 5 alpha-humulene 1.4 --- 0.2 +/- 0.1 6.1 +/- 0.8 2.4 +/- 0.3 7.5 +/- 0.7 54 +/- 3 77 +/- 9 longifolene 0.8 25 +/- 3 3.7 +/- 0.4 31 +/- 3 3.8 +/- 0.3 15 +/- 1 30 +/- 2 62 +/- 7 limonene 1.1 43 +/- 5 0.7 +/- 0.1 5.0 +/- 0.6 0.4 +/- 0.1 3.2 +/- 0.4 61 +/- 3e 113 +/- 17 myrcene 0.9 74 +/- 8f 0.7 +/- 0.1 4.5 +/- 0.5 22 +/- 2 3.9 +/- 0.4 134 +/- 10 100 +/- 17 methyl chavicol 0.8 52 +/- 6 0.7 +/- 0.1 7.9 +/- 1 0.7 +/- 0.1 25 +/- 2g 121 +/- 11 101 +/- 20 3-carene 0.8 35 +/- 4 1.6 +/- 0.2 5.4 +/- 0.6 9.3 +/- 0.9 5.1 +/- 0.6 95 +/- 5h 138 +/- 55 aromadendrene 1.4 65 +/- 8 2.9 +/- 0.3 12 +/- 2 4.8 +/- 0.5 4.1 +/- 0.4 69 +/- 7 74 +/- 14 alpha-pinene 1.1 16 +/- 2 1.4 +/- 0.2 4.5 +/- 0.5 6.3 +/- 0.6 3.4 +/- 0.4 91 +/- 14i 100 +/- 7 terpinolene 1.1 23 +/- 3 0.7 +/- 0.1 3.5 +/- 0.7 20 +/- 2 1 +/- 0.2 109 +/- 8 87 +/- 18 beta-pinenej 2.1 49 +/- 6 0.6 +/- 0.1 8.2 +/- 0.7 7.9 +/- 0.7 1.4 +/- 0.1 26 +/- 1 52 +/- 5 gamma-terpinene 1.1 17 +/- 2 1.2 +/- 0.2 8.3 +/- 0.8 5.3 +/- 0.5 4.5 +/- 0.5 130 +/- 10k 112 +/- 28 alpha-terpinene 1.0 7.8 +/- 2 0.7 +/- 0.1 6.1 +/- 1 3.1 +/- 0.4 2 +/- 0.3 61 +/- 4l 123 +/- 40 verbenone 1.1 32 +/- 2 2.1 +/- 0.3 8 +/- 0.8 13 +/- 1 6.9 +/- 0.6 92 +/- 4 79 +/- 17 linalool 1.0 43 +/- 5 1.1 +/- 0.1 3.2 +/- 0.4 25 +/- 2 17 +/- 2g 144 +/- 11 104 +/- 25 isoprenem 1.8 160 +/- 19f 1.9 +/- 0.3 4.6 +/- 0.6 0.4 +/- 0.1 5.7 +/- 0.7 g 15 +/- 1 101 - 114 +/- 22 aInitial hydrocarbon (ppb parent terpene) to NOx (ppb NO + NO2) ratio of the experiment. bGas-phase yields of CH2O (formaldehyde), C2H4O (acetaldehyde), CH2O2 (formic acid), C3H6O (acetone), and C2H4O2 (acetic acid), are expressed on a percent mole basis. Product yields > 20% are listed in bold. cUnidentified molar yields does not include the identified but uncalibrated ions associated with the dominant aldehydes formed from limonene, 3-carene, alpha-pinene, alpha-terpinene, and gamma-terpinene (Table 2). dTotal carbon balance calculated from the sum of the gas-phase products and SOA, assuming aerosol is 60% carbon. See text for explanation of uncertainty estimates. eYield of limononaldehyde was 68 +/- 7%. fSubject to significant error due to concentrations beyond range of calibrations. gLikely includes a contribution from glycolaldehyde (C2H4O2, MW = 60). hMolar yield of caronaldehyde was 77 +/- 8%. iThe midrange pinonaldehyde yield was used in the calculation. jThe nopinone yield from beta-pinene photooxidation was 17 +/- 2%. kYield of gamma-terpinaldehyde was 57 +/- 6%. lYield of alpha-terpinaldehyde was 19 +/- 2%. mMVK + MACR yield was 60 - 87 +/- 11% and 3-methylfuran yield was 3.6 +/- 0.4%.