Table 3. Gas-Phase Molar Yields and Carbon Balance (%) for the Ozonolysis Experiments Terpene Formaldehyde,% Yield Acetaldehyde,% Yield Formic Acid,% Yield Acetone,% Yield Acetic Acid, % Yield UnID,a % Yield C Balance,b % 3-carene 25 +/- 2 3.9 +/- 0.4 11 +/- 1 9.5 +/- 1 14 +/- 1 19 +/- 1 55 +/- 2 alpha-terpinene 4 +/- 2 1 +/- 0.3 9.6 +/- 2 6.3 +/- 1 9.5 +/- 2 31 +/- 2 58 +/- 4 beta-caryophyllenec 76 +/- 20 0.9 +/- 0.3 3.9 +/- 1 1.1 +/- 0.3 20 +/- 5 6.4 +/- 0.8 39 +/- 2 alpha-humulenec 3.5 +/- 1.1 0.9 +/- 0.3 0.4 +/- 0.2 1.2 +/- 0.4 12 +/- 1 9.5 +/- 0.8 33 +/- 2 alpha-pinened 28 +/- 3 2.9 +/- 0.3 7.5 +/- 0.7 5.9 +/- 0.5 8 +/- 0.9 15 +/- 1 67 +/- 3 terpinolene 29 +/- 3 9 +/- 0.8 4 +/- 0.4 44 +/- 4 5.8 +/- 0.6 81 +/- 9 77 +/- 13 beta-pinened 65 +/- 6 2.4 +/- 0.2 4 +/- 0.4 3.6 +/- 0.3 8.6 +/- 0.9 20 +/- 1 54 +/- 3 myrcene 51 +/- 5 15 +/- 2 3.9 +/- 0.4 23 +/- 2 5.3 +/- 0.5 92 +/- 10 69 +/- 14 methyl chavicol 61 +/- 5 ¦ 11 +/- 1 1.1 +/- 0.1 2.2 +/- 0.3 50 +/- 7 55 +/- 8 linalool 34 +/- 3 14 +/- 1 2.5 +/- 0.3 16 +/- 1 5.1 +/- 0.5 92 +/- 9 63 +/- 13 aSum of the yields of all product ions (m/z) listed in Table 1. bThe carbon balance (%) from identified gas-phase products (formaldehyde, formic acid, acetaldehyde, acetone, nopinone, and pinonaldehyde), plus the yield of the unidentified compounds, assuming a conservative number of C for each observed ion, and from the particle-phase, assuming the SOA is 60% C. The pinonaldehyde yield used for the C balance calculation was the lower-limit yield of 19%. cSeed aerosol was not used in the sesquiterpene experiments. dFrom alpha-pinene ozonolysis, the percent molar yield of pinonaldehyde was estimated to range from 19 +/- 2% to 34 +/- 3% (see text) and the molar yield of alpha-pinene oxide was 5.4 +/- 0.6%. From beta-pinene ozonolysis the yield of nopinone from was 17 +/- 2%.