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Theoretical Study of Electron Transfer Reactions of Solvated Electrons

Marcus, R. A. (1965) Theoretical Study of Electron Transfer Reactions of Solvated Electrons. In: Solvated Electron. Advances in Chemistry Series. No.50. American Chemical Society , Washington, DC, pp. 138-148. ISBN 9780841200517. http://resolver.caltech.edu/CaltechAUTHORS:20150930-101029562

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Abstract

The assumptions, equations and several applications of a recently formulated theory of electron transfer reactions of solvated electrons are outlined. The relationship of the reorganization terms to those of ordinary electron exchange and electrochemical reactions is described, together with the role played by an effective standard free energy of reaction. Applications include prediction of conditions under which chemiluminescence might be found and description of conditions under which reactions might not be diffusion-controlled.


Item Type:Book Section
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http://dx.doi.org/10.1021/ba-1965-0050.ch011DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ba-1965-0050.ch011PublisherArticle
Additional Information:© 1965 American Chemical Society. Received May 3, 1965. Supported by a grant from the National Science Foundation.
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Record Number:CaltechAUTHORS:20150930-101029562
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150930-101029562
Official Citation:Theoretical Study of Electron Transfer Reactions of Solvated Electrons R. A. MARCUS Solvated Electron. January 1, 1965, 138-148 DOI:10.1021/ba-1965-0050.ch011
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60603
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:30 Sep 2015 18:54
Last Modified:30 Sep 2015 18:54

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