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Energetic and Dynamical Aspects of Proton Transfer Reactions in Solution

Marcus, R. A. (1975) Energetic and Dynamical Aspects of Proton Transfer Reactions in Solution. Faraday Symposia of the Chemical Society, 10 . pp. 60-68. ISSN 0301-5696. http://resolver.caltech.edu/CaltechAUTHORS:20150930-121201711

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Abstract

Several energetic and dynamical aspects of proton transfers are treated. The effect of intrinsic barrier asymmetry on BEBO calculated Brönsted plots is investigated, and contributions to work terms are also considered. The dynamics of transfer of a light particle between two heavier ones is discussed for a particular potential energy surface, making use of classical trajectories, semiclassical concepts, and a previous quantum study. The question of nonequilibrium polarization of solvent is also considered.


Item Type:Article
Related URLs:
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http://dx.doi.org/10.1039/FS9751000060DOIArticle
http://pubs.rsc.org/en/content/articlelanding/1975/fs/fs9751000060PublisherArticle
Additional Information:© 1975 Royal Society of Chemistry. Received 19th May, 1975. This work was supported in part by the Office of Naval Research.
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Office of Naval Research (ONR)UNSPECIFIED
Record Number:CaltechAUTHORS:20150930-121201711
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150930-121201711
Official Citation:Energetic and dynamical aspects of proton transfer reactions in solution R. A. Marcus Faraday Symp. Chem. Soc., 1975, 10, 60-68 DOI: 10.1039/FS9751000060
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60607
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:30 Sep 2015 20:36
Last Modified:30 Sep 2015 20:36

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