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Solvolytic Reactivities of Some Secondary Alkyl Chlorides

Roberts, John D. (1949) Solvolytic Reactivities of Some Secondary Alkyl Chlorides. Journal of the American Chemical Society, 71 (5). pp. 1880-1881. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20150930-135820224

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Abstract

Despite numerous comparisons of the reactivities of saturated organic halides toward nucleophilic reagents relatively few investigations have been made of solvolytic reactivities of saturated halides under comparable conditions except for the series: methyl, ethyl, isopropyl, and t-butyl. Dostrovsky and Hughes have measured the solvolytic reaction rates of several alkyl bromides in aqueous alcohol and formic acid while Bartlett and Swain and Brown and Johanneson have reported relative reactivities for tertiary chlorides.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01173a522DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01173a522PublisherArticle
Additional Information:© 1949 American Chemical Society. Received November 20, 1948. [John D. Roberts] National Research Fellow in Chemistry, 1945-46.
Funders:
Funding AgencyGrant Number
National Research CouncilUNSPECIFIED
Issue or Number:5
Record Number:CaltechAUTHORS:20150930-135820224
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150930-135820224
Official Citation:Solvolytic Reactivities of Some Secondary Alkyl Chlorides John D. Roberts Journal of the American Chemical Society 1949 71 (5), 1880-1881 DOI: 10.1021/ja01173a522
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60621
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:07 Oct 2015 13:40
Last Modified:03 Oct 2019 08:58

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