Roberts, John D. and Armstrong, Rose and Trimble, R. F., Jr. and Burg, Marion (1949) The Use of Carbon-14 in the Determination of the Structures of Aldoketene Dimers. Journal of the American Chemical Society, 71 (3). pp. 843-847. ISSN 0002-7863. doi:10.1021/ja01171a023. https://resolver.caltech.edu/CaltechAUTHORS:20150930-135820789
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Abstract
The structures of aldoketene dimers prepared by the dehydrohalogenation of acyl halides have not been conclusively established. Recent infrared spectroscopic studies by Miller and Koch indicate that the parent compound, diketene, is probably an equilibrium mixture of compounds having structures II and III although IV could not be excluded as a component of the mixture by the infrared data.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1949 American Chemical Society. Received October 9, 1948. We wish to acknowledge the assistance of Miss Winifred Bennett with the radioactivity analyses and Mr. D. R. Smith with the preparation of the radioactive propionyl chloride. Assisted by the joint program of the Office of Naval Research and the Atomic Energy Commission. Presented at the St. Louis Meeting of the American Chemical Society, September 7, 1948. | |||||||||
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| Issue or Number: | 3 | |||||||||
| DOI: | 10.1021/ja01171a023 | |||||||||
| Record Number: | CaltechAUTHORS:20150930-135820789 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150930-135820789 | |||||||||
| Official Citation: | The Use of Carbon-14 in the Determination of the Structures of Aldoketene Dimers John D. Roberts, Rose. Armstrong, R. F. Trimble, and Marion. Burg Journal of the American Chemical Society 1949 71 (3), 843-847 DOI: 10.1021/ja01171a023 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 60623 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 07 Oct 2015 18:23 | |||||||||
| Last Modified: | 10 Nov 2021 22:36 |
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