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The Use of Carbon-14 in the Determination of the Structures of Aldoketene Dimers

Roberts, John D. and Armstrong, Rose and Trimble, R. F., Jr. and Burg, Marion (1949) The Use of Carbon-14 in the Determination of the Structures of Aldoketene Dimers. Journal of the American Chemical Society, 71 (3). pp. 843-847. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20150930-135820789

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Abstract

The structures of aldoketene dimers prepared by the dehydrohalogenation of acyl halides have not been conclusively established. Recent infrared spectroscopic studies by Miller and Koch indicate that the parent compound, diketene, is probably an equilibrium mixture of compounds having structures II and III although IV could not be excluded as a component of the mixture by the infrared data.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01171a023DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01171a023PublisherArticle
Additional Information:© 1949 American Chemical Society. Received October 9, 1948. We wish to acknowledge the assistance of Miss Winifred Bennett with the radioactivity analyses and Mr. D. R. Smith with the preparation of the radioactive propionyl chloride. Assisted by the joint program of the Office of Naval Research and the Atomic Energy Commission. Presented at the St. Louis Meeting of the American Chemical Society, September 7, 1948.
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Office of Naval Research (ONR)UNSPECIFIED
Atomic Energy CommissionUNSPECIFIED
Issue or Number:3
Record Number:CaltechAUTHORS:20150930-135820789
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150930-135820789
Official Citation:The Use of Carbon-14 in the Determination of the Structures of Aldoketene Dimers John D. Roberts, Rose. Armstrong, R. F. Trimble, and Marion. Burg Journal of the American Chemical Society 1949 71 (3), 843-847 DOI: 10.1021/ja01171a023
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60623
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:07 Oct 2015 18:23
Last Modified:03 Oct 2019 08:58

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